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表单
solid
质量水平
反应适用性
core: ruthenium
reagent type: catalyst
SMILES字符串
[Ru+2](=C2N(CCN2c4c(cc(cc4C)C)C)c3c(cc(cc3C)C)C)=Cc1c(ccc(c1)[S](=O)(=O)N(C)C)OC(C)C.[Cl-].[Cl-]
InChI
1S/C21H26N2.C12H17NO3S.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-9(2)16-12-7-6-11(8-10(12)3)17(14,15)13(4)5;;;/h9-12H,7-8H2,1-6H3;3,6-9H,1-2,4-5H3;2*1H;/q;;;;+2/p-2
InChI key
OXLURKCRXVAJQS-UHFFFAOYSA-L
相关类别
应用
詹氏催化剂-1B(Hoveyda-Grubbs型催化剂)可用于:
- 制备复合烯烃复分解反应催化剂,通过在分子筛上固定而获得更高的催化活性
- 作为合成发散型树形分子的催化剂
- 关环复分解 (RCM) 反应。
储存分类代码
13 - Non Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Stereoselectivity in N-iminium ion cyclization: development of an efficient synthesis of ?-cephalotaxine
Organic Letters, 17(18), 4444-4447 (2015)
Hoveyda-Grubbs type metathesis catalyst immobilized on mesoporous molecular sieves-The influence of pore size on the catalyst activity
Catalysis Today, 179(1), 123-129 (2012)
Macromolecular rapid communications, 35(3), 317-322 (2013-12-21)
The combination of the Passerini reaction and olefin cross-metathesis is shown to be a very useful approach for the divergent synthesis of dendrimers. Castor oil-derived platform chemicals, such as 10-undecenoic acid and 10-undecenal, are reacted in a Passerini reaction with
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