质量水平
形式
solid
反应适用性
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
浓度
60% Pd
mp
678-680 °C (lit.)
密度
4 g/mL at 25 °C (lit.)
SMILES字符串
Cl[Pd]Cl
InChI
1S/2ClH.Pd/h2*1H;/q;;+2/p-2
InChI key
PIBWKRNGBLPSSY-UHFFFAOYSA-L
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应用
氯化钯（II）可用于催化以下反应：
- 在改良Sonogashira-Cassar-Heck条件下，末端炔烃与芳基碘化物或溴化物之间的交叉偶联反应。
- 有机碲与一氧化碳的羰基化反应，形成相应的甲基羧酸酯。
- 烯丙基酯在乙酸中的异构化反应。
- 胺的酰化反应，形成异氰酸酯。
其他说明
综述
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Palladium (II)-catalyzed exchange and isomerization reactions. III. Allylic esters isomerization in acetic acid catalyzed by palladium (II) chloride.
Henry P M.
Journal of the American Chemical Society, 94(15), 5200-5206 (1972)
Carbonylation of Amines in the Presence of Palladium (II) Chloride. A New Route to Isocyanates.
Stern E. W and Spector M. L.
The Journal of Organic Chemistry, 31(2), 596-597 (1966)
R.F. Heck
Accounts of Chemical Research, 12, 146-146 (1979)
Palladium (II) Chloride and a (Dipyridin?2?ylmethyl) amine?Derived Palladium (II) Chloride Complex as Highly Efficient Catalysts for the Synthesis of Alkynes in Water or in NMP and of Diynes in the Absence of Reoxidant.
Gil?Molto J and Najera C.
European Journal of Organic Chemistry, 2005(19), 4073-4081 (2005)
Palladium (II) chloride catalyzed carbonylation of organic tellurides with carbon monoxide.
Ohe K, et al.
The Journal of Organic Chemistry, 52(22), 4859-4863 (1987)
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