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Merck
CN
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文件

安全信息

760455

Sigma-Aldrich

Ethyl 2-(phenylcarbonothioylthio)propionate

97% (HPLC)

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别名:
2-[(Phenylthioxomethyl)thio]propanoic acid ethyl ester, Ethyl 2-(phenylcarbonothioylthio)propanoate
经验公式（希尔记法）:
C12H14O2S2
CAS号:
412015-83-9
分子量:
254.37
MDL编号:
MFCD22200547
UNSPSC代码:
12352100
PubChem化学物质编号:
329766866
NACRES:
NA.23

检测方案

97% (HPLC)

形式

liquid

折射率

n20/D 1.611

密度

1.163 g/mL at 25 °C

储存温度

2-8°C

SMILES字符串

CCOC(=O)C(C)SC(=S)c1ccccc1

InChI

1S/C12H14O2S2/c1-3-14-11(13)9(2)16-12(15)10-7-5-4-6-8-10/h4-9H,3H2,1-2H3

InChI key

NXWVPIWRMPQYEX-UHFFFAOYSA-N

一般描述

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

应用

RAFT agent for controlled radical polymerization; especially suited for methacrylates and methacrylamides; Chain Transfer Agent (CTA)
Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

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Micro Review of RAFT Polymerization

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

实验方案

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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