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质量水平
形式
paste
质量
moistened with water
包含
~50% water as stabilizer
反应适用性
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
环保替代产品特性
Designing Safer Chemicals
Catalysis
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sustainability
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浓度
5% Pd (based on dry substance)
环保替代产品分类
, Aligned
SMILES字符串
[Pd]
InChI
1S/Pd
InChI key
KDLHZDBZIXYQEI-UHFFFAOYSA-N
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一般描述
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
应用
Palladium on activated charcoal can be used as a heterogeneous catalyst:
- To synthesize methyl esters via oxidative esterification of primary alcohols.
- In the hydrogenation of phenol to cyclohexanone.
- For carbonylation of iodoanilines with amines and trimethyl orthoformate to prepare quinazolinones.
- In the hydrodehalogenation of aromatic halides to form arenes in aqueous media.
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
Pd/C-catalyzed hydrodehalogenation of aromatic halides in aqueous solutions at room temperature under normal pressure.
Xia C
Catalysis Communications, 5(8), 383-386 (2004)
Oxidative Esterification of Primary Alcohols with a Pd/Bi/Te Catalyst
Uozumi Y and Osako T
Synfacts, 10, 0108-0108 (2014)
Highly selective palladium supported catalyst for hydrogenation of phenol in aqueous phase
Perez Y, et al.
Catalysis Communications, 12, 1071-1074 (2011)
Pd/C as an efficient heterogeneous catalyst for carbonylative four-component synthesis of 4 (3 H)-quinazolinones
Natte K, et al.
Catalysis Science & Technology, 5, 4474-4480 (2015)
Development of GSKDevelopment of GSK's reagent guides ? embedding sustainability into reagent selections reagent guides ? embedding sustainability into reagent selection.
Adams JP, et al.
Green Chemistry, 15, 1542-1549 (2013)
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