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化学文摘社编号:
MDL number:
UNSPSC Code:
12352000
PubChem Substance ID:
NACRES:
NA.22
Beilstein/REAXYS Number:
5199887
产品名称
OXONE® 四丁基铵盐, technical, ~1.6% active oxygen basis
SMILES string
OS([O-])(=O)=O.[O-]S([O-])(=O)=O.OS(=O)(=O)O[O-].OS(=O)(=O)O[O-].CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC
InChI
1S/5C16H36N.2H2O5S.2H2O4S/c5*1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2*1-5-6(2,3)4;2*1-5(2,3)4/h5*5-16H2,1-4H3;2*1H,(H,2,3,4);2*(H2,1,2,3,4)/q5*+1;;;;/p-5
InChI key
IGMBKNUVZFAHJM-UHFFFAOYSA-I
grade
technical
form
powder
reaction suitability
reagent type: oxidant
concentration
~1.6% (active oxygen)
Quality Level
mp
144-147 °C
Other Notes
形成的 Oxone 特别适合于 CH2Cl2 中敏感化合物的氧化反应;由醇和 THF 通过自由基偶联反应制备 2-四氢呋喃基醚的试剂
Application
Reagent for:
- Oxidation of Hantzsch 1,4-Dihydropyridines catalyzed by manganese(III) Schiff Base complexes
- Epoxidation of alkenes
- Oxidation of sulfides and olefins
- Oxidation of alcohols
- Oxidation of aromatic amines for synthesis of azoxy arenes
Legal Information
OXONE is a registered trademark of E. I. du Pont de Nemours and Company
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
B.M. Trost et al.
The Journal of Organic Chemistry, 53, 532-532 (1988)
J.C. Jung et al.
Tetrahedron Letters, 34, 3581-3581 (1993)
R. Cosstick et al.
Tetrahedron Letters, 30, 4693-4693 (1989)
R. Annunziata et al.
The Journal of Organic Chemistry, 55, 1901-1901 (1990)
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