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文件

757136

Sigma-Aldrich

双（草酸）硼酸锂

greener alternative
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别名:
LiBOB, 双（乙二醇）硼酸锂, 双（草酸）硼酸锂
线性分子式:
LiB(C2O4)2
CAS号:
244761-29-3
分子量:
193.79
MDL编号:
MFCD07776904
UNSPSC代码:
26111700
PubChem化学物质编号:
329766649
NACRES:
NA.23

形式

powder or crystals

质量水平

100

环保替代产品特性

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

>300 °C (lit.)

应用

battery manufacturing

环保替代产品分类

Enabling,

SMILES字符串

[Li+].O=C1O[B-]2(OC1=O)OC(=O)C(=O)O2

InChI

1S/C4BO8.Li/c6-1-2(7)11-5(10-1)12-3(8)4(9)13-5;/q-1;+1

InChI key

NVQAYVUCVASGDK-UHFFFAOYSA-N

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相关类别

一般描述

双(草酸根)硼酸锂(LiBOB)是一类电解材料，可用于制造锂离子电池。锂离子电池由具有充放电循环的阳极、阴极和电解液组成。这些材料能形成更环保的可持续性电能储存电池。
我们致力于为您提供更环保的替代产品，以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型，提高了能源效率。点击此处，查看更多详情。

应用

LiBOB是一种新型的锂离子电池硼基锂盐电解质材料。它对环境友好，具有良好的成膜性能和高热稳定性，并与各种阳极和金属氧化物阴极兼容。
LiBOB是热稳定电解质，可用于保护锂离子电池中的石墨基阳极材料。它显示了良好的电化学性能，放电容量保持率约为83%。

法律信息

Albemarle US Inc产品

相关产品

产品编号
说明
价格

450227

六氟磷酸锂, battery grade, ≥99.99% trace metals basis

774138

二氟硼酸锂

809942

碳酸二甲酯, battery grade, ≥99.9%, acid <10 ppm, H2O <10 ppm

809950

碳酸亚乙酯, battery grade, ≥99%, acid <10 ppm, H2O <10 ppm

809969

碳酸丙烯酯, battery grade, ≥99%, acid <10 ppm, H2O <10 ppm

809977

碳酸亚乙烯酯, battery grade, 99.5%, acid <200 ppm, H2O <100 ppm

809934

碳酸甲乙酯, battery grade, 99.9%, acid <10 ppm, H2O <10ppm

900018

碳酸二乙酯, battery grade, ≥99%, acid <10 ppm, H2O <10 ppm

901686

氟代碳酸乙烯酯, battery grade, ≥99%, acid <200 ppm, anhydrous

919977

双(三氟甲烷)磺酰亚胺 锂盐, anhydrous, 99.99% trace metals basis

象形图

CorrosionExclamation mark
GHS05,GHS07

警示用语：

Danger

危险声明

H302,H317,H318

危险分类

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Sens. 1A

WGK

WGK 1

分析证书(COA)

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Wengao Zhao et al.
ChemSusChem, 11(13), 2211-2220 (2018-05-03)
The long-term cycling performance, rate capability, and voltage stability of lithium (Li) metal batteries with LiNi0.76 Mn0.14 Co0.10 O2 (NMC76) cathodes is greatly enhanced by lithium bis(oxalato)borate (LiBOB) additive in the LiPF6 -based electrolyte. With 2 % LiBOB in the electrolyte
R Verrelli et al.
Physical chemistry chemical physics : PCCP, 19(38), 26435-26441 (2017-09-26)
Layered MgMoN
Lithium bis (oxalato) borate stabilizes graphite anode in propylene carbonate
Xu K, et al.
Electrochemical and Solid-State Letters, 5(11), A259-A259 (2002)
Shoichi Matsuda et al.
Scientific reports, 9(1), 6211-6211 (2019-04-19)
Data-driven material discovery has recently become popular in the field of next-generation secondary batteries. However, it is important to obtain large, high quality data sets to apply data-driven methods such as evolutionary algorithms or Bayesian optimization. Combinatorial high-throughput techniques are
Snehashis Choudhury et al.
Nature communications, 10(1), 4398-4398 (2019-09-29)
Electrochemical cells based on alkali metal anodes are receiving intensive scientific interest as potentially transformative technology platforms for electrical energy storage. Chemical, morphological, mechanical and hydrodynamic instabilities at the metal anode produce uneven metal electrodeposition and poor anode reversibility, which, are among the many
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