756792
3,7-Diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane
97%
别名:
DAPTA
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关于此项目
经验公式（希尔记法）:
C9H16N3O2P
化学文摘社编号:
分子量:
229.22
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
InChI
1S/C9H16N3O2P/c1-8(13)11-3-10-4-12(9(2)14)7-15(5-10)6-11/h3-7H2,1-2H3
SMILES string
CC(=O)N1CN2CN(CP(C2)C1)C(C)=O
InChI key
MYJHMDGWZWBLCK-UHFFFAOYSA-N
assay
97%
form
solid
mp
183 °C (decomposition)
functional group
phosphine
Quality Level
Application
3,7-Diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane is a phosphine ligand and acetylized derivative of 1,3,5-triaza-7-phosphaadamantane that can be used:
- As a ligand in the synthesis of diiron dithiolate complexes of Fe-only hydrogenase to improve the hydro- and protophilicity of the active site.
- To prepare (η6-arene)-ruthenium(II) complex, which is employed as a catalyst in the reduction of allylic alcohols.
- As a ligand in the synthesis of water-soluble cis- and trans-Pt(II) and Pd(II) metal complexes.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Ruthenium-catalyzed reduction of allylic alcohols using glycerol as solvent and hydrogen donor
Diaz-Alvarez AE, et al.
Catalysis Communications, 13(1), 91-96 (2011)
Yanfang Song et al.
Cancer research, 77(7), 1611-1622 (2017-01-14)
Mice housed in an enriched environment display a tumor-resistant phenotype due to eustress stimulation. However, the mechanisms underlying enriched environment-induced protection against cancers remain largely unexplained. In this study, we observed a significant antitumor effect induced by enriched environment in
An approach to water-soluble hydrogenase active site models: Synthesis and electrochemistry of diiron dithiolate complexes with 3, 7-diacetyl-1, 3, 7-triaza-5-phosphabicyclo [3.3. 1] nonane ligand (s)
Na Y, et al.
Journal of Organometallic Chemistry, 691(23), 5045-5051 (2006)
Synthesis and characterization of Pt(II) and Pd(II) PTA and DAPTA complexes
Braddock-Wilking J, et al.
Polyhedron, 79(1), 16-28 (2014)
Chen Chen et al.
Cellular and molecular neurobiology, 39(5), 651-669 (2019-04-15)
CKLF1 is a chemokine with increased expression in ischemic brain, and targeting CKLF1 has shown therapeutic effects in cerebral ischemia model. Microglia/macrophage polarization is a mechanism involved in poststroke injury expansion. Considering the quick and obvious response of CKLF1 and
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