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Merck
CN

753106

Benzyl 1H-pyrrole-1-carbodithioate

97% (HPLC)

别名:

1H-Pyrrole-1-carbodithioic acid phenylmethyl ester

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关于此项目

经验公式（希尔记法）:
C12H11NS2
化学文摘社编号:
60795-38-2
分子量:
233.35
NACRES:
NA.23
PubChem Substance ID:
329766335
UNSPSC Code:
12352100
MDL number:
MFCD00972165

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产品名称

Benzyl 1H-pyrrole-1-carbodithioate, 97% (HPLC)

InChI

1S/C12H11NS2/c14-12(13-8-4-5-9-13)15-10-11-6-2-1-3-7-11/h1-9H,10H2

SMILES string

S=C(SCc1ccccc1)n2cccc2

InChI key

AGCPVOYGTAIJAP-UHFFFAOYSA-N

assay

97% (HPLC)

form

liquid

refractive index

n20/D 1.678

density

1.186 g/mL at 25 °C

storage temp.

2-8°C

Application

RAFT agent for controlled radical polymerization; Chain Transfer Agent (CTA)
RAFT agent for controlled radical polymerization; well-suited for polymerization of vinyl esters and vinyl amides (LAMs)

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Legal Information

Sold for Research Purposes only: See sigma-aldrich.com/raftlicense Patents: WO98/01478; WO99/311444

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H315,H319

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCJ0255
MKBJ5101V

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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

商品

Protein- and Peptide- Polymer Conjugates by RAFT Polymerization

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

Micro Review of RAFT Polymerization

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

实验方案

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

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