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Merck
CN

753106

Sigma-Aldrich

Benzyl 1H-pyrrole-1-carbodithioate

97% (HPLC)

别名:

1H-Pyrrole-1-carbodithioic acid phenylmethyl ester

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About This Item

经验公式(希尔记法):
C12H11NS2
CAS号:
分子量:
233.35
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.23

方案

97% (HPLC)

表单

liquid

折射率

n20/D 1.678

密度

1.186 g/mL at 25 °C

储存温度

2-8°C

SMILES字符串

S=C(SCc1ccccc1)n2cccc2

InChI

1S/C12H11NS2/c14-12(13-8-4-5-9-13)15-10-11-6-2-1-3-7-11/h1-9H,10H2

InChI key

AGCPVOYGTAIJAP-UHFFFAOYSA-N

一般描述

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.
Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

应用

RAFT agent for controlled radical polymerization; Chain Transfer Agent (CTA)
RAFT agent for controlled radical polymerization; well-suited for polymerization of vinyl esters and vinyl amides (LAMs)

法律信息

销售仅用于研究目的:请访问sigma-aldrich.com/raftlicense 专利: WO98/01478; WO99/311444

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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分析证书(COA)

Lot/Batch Number

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访问文档库

RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

商品

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

实验方案

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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