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安全信息

749125

Sigma-Aldrich

Cobalt(II) oxo pivalate

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别名:

Basic cobalt(II) pivalate, Cobalt, hexakis[μ-(2,2-dimethylpropanoato-κO:κO′)]hexakis[μ3-(2,2-dimethylpropanoato-κO:κO:κO′)]di-μ4-oxoocta-, Tetrameric Co cluster

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About This Item

经验公式（希尔记法）:
C60H108Co8O26
CAS号:
301663-94-5
分子量:
1716.95
MDL编号:
MFCD22200509
UNSPSC代码:
26111700
PubChem化学物质编号:
329765968
NACRES:
NA.23

表单

powder

质量水平

100

环保替代产品特性

Design for Energy Efficiency
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sustainability

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环保替代产品分类

Enabling,

SMILES字符串

CC(C)(C)C(=O)O[Co-]1O[Co-](O\C(=[O+]/[Co-](OC(=O)C(C)(C)C)O\C(=[O+]/[Co-](OC(=O)C(C)(C)C)OC(=O)C(C)(C)C)C(C)(C)C)C(C)(C)C)[O+]=C(O[Co-]2O[Co-](O\C(=[O+]\1)C(C)(C)C)\[O+]=C(\O[Co-](OC(=O)C(C)(C)C)\[O+]=C(\O[Co]OC(=[O+]2)C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C

InChI

1S/12C5H10O2.8Co.2O/c12*1-5(2,3)4(6)7;;;;;;;;;;/h12*1-3H3,(H,6,7);;;;;;;;;;/q;;;;;;;;;;;;4*+1;4*+2;;/p-12

InChI key

PBKALLJUIAKYSI-UHFFFAOYSA-B

相关类别

一般描述

Cobalt(II) oxo pivalate is a dinuclear complex that is typically formed by the direct reaction of cobalt carbonate with pivalic acid, followed by crystallization from MeCN. Its structure has two Co(II) sites bridged by two 2,11-carboxylates (Harris notation) and an oxygen atom.
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应用

Synthesis of trinuclear complex [Co3(Piv)2L12L22] by reacting cobalt(II)pivalate with spin labeled Schiff base has been reported in a study.

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKBJ4129V

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Synthetic and structural studies of cobalt-pivalate complexes
Aromi G, et al.
Chemistry?A European Journal , 9(20), 5142-5161 (2003)
Redox-Induced Change in the Ligand Coordination Mode.
Ovcharenko V, et al.
Inorganic Chemistry, 53(19), 10033-10035 (2014)
Steffen Hausdorf et al.
The journal of physical chemistry. A, 112(33), 7567-7576 (2008-07-26)
The contributions of terephthalic acid and Zn(2+)-coordinated water in N,N-diethylformamide (DEF) to the overall proton activity in the synthesis of MOF-5 (Zn4O(BDC)3, BDC = 1,4-benzenedicarboxylate) were quantitatively determined by combined electrochemical and UV-vis spectroscopic measurements. Structural transformations of zinc carboxylate-based
Steffen Hausdorf et al.
Dalton transactions (Cambridge, England : 2003), 7(7), 1107-1113 (2009-03-27)
An ethynylene diisophthalic acid linker molecule was synthesized and used to form a zinc carboxylate-based metal organic framework (MOF) with very large pores and unit cell volume resulting from the unusual combination of structurally different inorganic units forming the secondary
Steffen Hausdorf et al.
Journal of the American Chemical Society, 132(32), 10978-10981 (2010-08-12)
A simple two-component procedure was developed to synthesize not only classical zinc-based IRMOFs represented by MOF-5 but also the cobalt and beryllium homologues of this most prominent MOF. The procedure is the first manifestation of mirroring the IRMOF series with

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