所有图片(1)
About This Item
经验公式（希尔记法）:
C21H22NP
CAS号:
分子量:
319.38
MDL编号:
UNSPSC代码:
12352116
PubChem化学物质编号:
NACRES:
NA.22
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表单
solid
旋光性
[α]/D -138.0°, c = 0.5% in chloroform
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
mp
105-109 °C
官能团
phosphine
储存温度
20-25°C
SMILES字符串
C[C@@H](N)[C@H](P(c1ccccc1)c2ccccc2)c3ccccc3
InChI
1S/C21H22NP/c1-17(22)21(18-11-5-2-6-12-18)23(19-13-7-3-8-14-19)20-15-9-4-10-16-20/h2-17,21H,22H2,1H3/t17-,21+/m1/s1
InChI key
JWZAIGGNEGTDMG-UTKZUKDTSA-N
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
D. Amoroso, T.W. Graham et al.
Aldrichimica Acta, 41, 1-1 (2008)
T. Hayashi, M. Konishi et al.
The Journal of Organic Chemistry, 48, 2195-2195 (1983)
Masato Ito et al.
Angewandte Chemie (International ed. in English), 48(7), 1324-1327 (2009-01-09)
Awakening of the Cp one: The bifunctional complex 1 facilitates the interaction with substrates bearing less electrophilic carbon atoms than ketones, epoxides, and imides. The title reaction was applicable to the reduction of Evans' asymmetric alkylation products to the chiral
A Saitoh et al.
The Journal of organic chemistry, 65(14), 4227-4240 (2000-07-13)
A new class of chiral amidine-phosphine hybrid ligands 7a,b, which are readily accessible from the corresponding alpha-amino acids, were developed. A versatility for construction of new ligands is desirable, by which a variety of reactions and substrates become applicable. Indeed
Isaac J Krauss et al.
Organic letters, 5(18), 3201-3203 (2003-08-29)
[reaction: see text] A new ligand for Cu-catalyzed enantioselective additions of dialkylzincs to cyclic enones has been developed. In addition to providing good to excellent enantioselectivities with a range of cyclic enones and dialkylzincs, the ligand has several notworthy features:
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