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746347

Sigma-Aldrich

Dichlorotriphenylphosphine[2-(diphenylphosphino)-N-(2-pyridinylmethyl)ethanamine]ruthenium(II)

greener alternative

97%

别名:

Ru-PNN catalyst

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About This Item

经验公式（希尔记法）:
C38H36Cl2N2P2Ru
CAS号:
1388712-91-1
MDL编号:
MFCD26960800
UNSPSC代码:
12161600
PubChem化学物质编号:
329765760
NACRES:
NA.22

质量水平

100

方案

97%

表单

solid

反应适用性

core: ruthenium
reagent type: catalyst

环保替代产品特性

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

275-295 °C

环保替代产品分类

Aligned,

SMILES字符串

Cl[Ru]Cl.[H]N(CCP(C1=CC=CC=C1)C2=CC=CC=C2)CC3=NC=CC=C3.P(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6

InChI

1S/C20H21N2P.C18H15P.2ClH.Ru/c1-3-10-19(11-4-1)23(20-12-5-2-6-13-20)16-15-21-17-18-9-7-8-14-22-18;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h1-14,21H,15-17H2;1-15H;2*1H;/q;;;;+2/p-2

InChI key

JFYJJNHKCBDTMZ-UHFFFAOYSA-L

相关类别

一般描述

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

应用

Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents.

From Esters to Alcohols and Back with Ruthenium and Osmium Catalysts

法律信息

This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.

象形图

Skull and crossbones
GHS06

警示用语：

Danger

危险声明

H302 + H312,H331

危险分类

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCW7470
MKCQ3302
MKBQ2005V

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访问文档库

Spasyuk, D.;
Angewandte Chemie (International Edition in English), 2772-2772 (2012)

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