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746339

Sigma-Aldrich

二氯三苯基膦[双（2-（乙硫基）乙基）胺]钌（II）

greener alternative

97%

别名:

Ru-SNS catalyst

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About This Item

经验公式（希尔记法）:
C26H34Cl2NPRuS2
CAS号:
1462397-86-9
分子量:
627.63
MDL编号:
MFCD26960799
UNSPSC代码:
12161600
PubChem化学物质编号:
329765759
NACRES:
NA.22

质量水平

100

方案

97%

表单

solid

反应适用性

core: ruthenium
reagent type: catalyst

环保替代产品特性

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

300-310 °C

环保替代产品分类

Aligned,

SMILES字符串

CCSCCN([H])CCSCC.Cl[Ru]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

InChI

1S/C18H15P.C8H19NS2.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-10-7-5-9-6-8-11-4-2;;;/h1-15H;9H,3-8H2,1-2H3;2*1H;/q;;;;+2/p-2

InChI key

ZQGMNGJIEYHKBR-UHFFFAOYSA-L

相关类别

一般描述

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

应用

Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents.

Replacing Phosphorus with Sulfur for the Efficient Hydrogenation of Esters
Catalyst for the hydrogenation of esters to alcohols.

其他说明

"The mer-SNS complexes form isomers in solution. This is due to the different arrangements of the SEt groups relative to the SNS ligand plane. Two of the isomers have eclipsed SEt groups (arranged on one side of the SNS plane), and the third isomer has staggered SEt groups (occupying the opposite sides of the SNS plane)."

法律信息

This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.

象形图

Skull and crossbones
GHS06

警示用语：

Danger

危险声明

H302 + H312,H331

危险分类

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

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分析证书(COA)

Lot/Batch Number
MKCR2408
MKCK5335
MKBQ2000V

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Denis Spasyuk et al.
Angewandte Chemie (International ed. in English), 52(9), 2538-2542 (2013-01-29)
Catalyst tune-up: A readily available, air-stable amino-sulfide catalyst, [RuCl(2)(PPh(3)){HN(C(2)H(4)SEt)(2)}], has been developed. This complex displays outstanding efficiency for the hydrogenation of a broad range of substrates with C=X bonds (esters, ketones, imines), as well as for the acceptorless dehydrogenative coupling

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