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Merck
CN
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安全信息

745820

Sigma-Aldrich

二氟{3-乙基-5- [1-(4-乙基-3,5-二甲基-2H-吡咯-2-亚甲基-N)乙基] -2,4-二甲基-1H-吡咯并-N}硼

98% (HPLC)

别名:

1,3,5,7,8-Pentamethyl-2,6-diethylpyrromethene-difluoroborate, 2,6-Diethyl-1,3,5,7,8-pentamethylpyrromethene-boron difluoride, 3-Ethyl-5-[1-(4-ethyl-3,5-dimethyl-2H-pyrrol-2-ylidene)ethyl]-2,4-dimethyl-1H-pyrrole, boron complex, Exciton Pyrromethene 567, P 567, Pyrromethene 567

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About This Item

经验公式（希尔记法）:
C18H25BF2N2
CAS号:
131083-16-4
分子量:
318.21
UNSPSC代码:
12352103
PubChem化学物质编号:
329765014
NACRES:
NA.23

方案

98% (HPLC)

表单

solid

mp

208-213 °C

荧光

λex 522 nm

SMILES字符串

CC(C1=C(C)C(CC)=C(C)N1B(F)2F)=C3[N]2=C(C)C(CC)=C3C

InChI

1S/C18H25BF2N2/c1-8-15-10(3)17-12(5)18-11(4)16(9-2)14(7)23(18)19(20,21)22(17)13(15)6/h8-9H2,1-7H3

InChI key

DZSMVBDAUBBZJD-UHFFFAOYSA-N

一般描述

Difluoro{3-ethyl-5-[1-(4-ethyl-3,5-dimethyl-2H-pyrrol-2-ylidene-N)ethyl]-2,4-dimethyl-1H-pyrrolato-N}boron is a pyrromethene dye that is majorly used in liquid and solid state lasers. Its properties include low intersystem crossing and low triplet-triplet absorption which results in a high fluorescent quantum yields.

应用

BODIPY laser dyes are used to generate fluorescent conjugates of proteins; nucleotides; oligonucleotides and dextrans; and to prepare fluorescent enzyme substrates; fatty acids; phospholipids; lipopolysaccharides; receptor ligands and polystyrene microspheres.

Used for solid-state dye laser devices.
Difluoro{3-ethyl-5-[1-(4-ethyl-3,5-dimethyl-2H-pyrrol-2-ylidene-N)ethyl]-2,4-dimethyl-1H-pyrrolato-N}boron can used in the fabrication of lasers for a variety of applications such as optoelectronics, and high intensity data storage.

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315,H319,H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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分析证书(COA)

Lot/Batch Number
MKBQ1675V
MKCQ1407

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Leonid M Goldenberg et al.
Advanced materials (Deerfield Beach, Fla.), 24(25), 3339-3343 (2012-06-01)
Distributed feedback (DFB) lasers are produced directly in fluorescent azobenzene-containing materials using a single holographic optical step. Surface relief grating capable of producing images in fluorescence microscopy can be holographically formed in a number of materials.
Pyrromethene-HEMA-based photopolymerizable holographic recording material
Blaya S, et al.
Optics Communications, 228(1-3), 55-61 (2003)
The concentration dependence of the normalized photostability of 1, 3, 5, 7, 8-pentamethyl-2, 6-di-t-butylpyrromethene-difluoroborate complex (PM-597) methanol solutions
Sisk WN and Sanders W
Journal of Photochemistry and Photobiology A: Chemistry, 167(2-3), 185-189 (2004)
Influence of plasmon resonance in silver nanoparticles on the properties of stimulated emission of 1, 3, 5, 7, 8-pentamethyl-2, 6-diethylpyrromethene-difluoroborate molecules in film of porous aluminum oxide
Ibrayev NK and Aimukhanov AK
Optics & Laser technology, 115(2-3), 246-250 (2019)
Alexander B Nepomnyashchii et al.
Accounts of chemical research, 45(11), 1844-1853 (2012-04-21)
BODIPY (boron dipyrromethene) dyes are unique materials with spectroscopic and electrochemical properties comparable to those of aromatic hydrocarbons. Electrochemical studies are useful in understanding the redox properties of these materials and finding structure-stability relations for the radical ions; along with
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