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Merck
CN

745480

Sigma-Aldrich

Zinc isopropylsulfinate

95%

别名:

Baran Isopropylation Reagent, Baran IPS Reagent, Bis((isopropylsulfinyl)oxy)zinc, IPS

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About This Item

经验公式(希尔记法):
C6H14O4S2Zn
分子量:
279.69
MDL编号:
UNSPSC代码:
12352001
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

95%

表单

solid

反应适用性

reaction type: Allylation
reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation

reagent type: diversification reagent

mp

161-166 °C

官能团

sulfinic acid

SMILES字符串

CC(C)S(=O)O[Zn]OS(=O)C(C)C

InChI

1S/2C3H8O2S.Zn/c2*1-3(2)6(4)5;/h2*3H,1-2H3,(H,4,5);/q;;+2/p-2

InChI key

PEEMMWYYSHSBTQ-UHFFFAOYSA-L

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应用

Zinc isopropylsulfinate (IPS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.


Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

联系

Frequently Asked Questions are available for this Product.

制备说明

may contain up to 1 mole eq ZnCl2

其他说明

Previously sold under product number L511161

警示用语:

Danger

危险声明

危险分类

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

靶器官

Respiratory system

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Christopher A Barwacz et al.
The International journal of oral & maxillofacial implants, 33(5), 1126-1135 (2018-09-20)
To evaluate the influence that three different implant-abutment interface designs had on peri-implant mucosal outcomes as assessed by the pink esthetic score (PES) 3 years after delayed implant placement and immediate provisionalization. Adult subjects (n = 141) requiring replacement of
Elisa Zamboni et al.
eLife, 9 (2020-11-11)
Adapting to the environment statistics by reducing brain responses to repetitive sensory information is key for efficient information processing. Yet, the fine-scale computations that support this adaptive processing in the human brain remain largely unknown. Here, we capitalise on the
Elisabeth Maurer et al.
Medical mycology, 57(3), 351-362 (2018-06-21)
Mucorales can cause cutaneous to deep-seated infections, mainly in the immunocompromised host, resulting in high mortality rates due to late and inefficient treatment. In this study, Galleria mellonella larvae were evaluated as a heterologous invertebrate host to study pathogenicity of
Rie Poulsen et al.
Trials, 18(1), 579-579 (2017-12-05)
Common mental disorders are important contributors to the global burden of disease and cause negative effects on both the individual and society. Stress-related disorders influence the individual's workability and cause early retirement pensions in Denmark. There is no clear evidence
Q van Geest et al.
NeuroImage. Clinical, 19, 507-515 (2018-07-10)
To explore the added value of dynamic functional connectivity (dFC) of the default mode network (DMN) during resting-state (RS), during an information processing speed (IPS) task, and the within-subject difference between these conditions, on top of conventional brain measures in

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Rapidly diversify (hetero)aromatic scaffolds for chemical industry needs amid resource and time constraints, ensuring efficiency.

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