跳转至内容
Merck
CN

744557

Sigma-Aldrich

5H-二苯并[a,d]环庚烯-5-基胺

95%

别名:

5-Amino-5H-dibenzo[a,d]cycloheptene, 5H-Dibenzo[a,d]cyclohepten-5-amine, trop-NH2

登录查看公司和协议定价


About This Item

经验公式(希尔记法):
C15H13N
CAS号:
分子量:
207.27
Beilstein:
2722512
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:

方案

≥95% (HPLC)
95%

表单

powder

储存温度

2-8°C

SMILES字符串

NC1c2ccccc2C=Cc3ccccc13

InChI

1S/C15H13N/c16-15-13-7-3-1-5-11(13)9-10-12-6-2-4-8-14(12)15/h1-10,15H,16H2

InChI key

HKLYXHWNPAGMMW-UHFFFAOYSA-N

包装

Bottomless glass bottle. Contents are inside inserted fused cone.

象形图

Skull and crossbonesEnvironment

警示用语:

Danger

危险声明

预防措施声明

危险分类

Acute Tox. 3 Oral - Aquatic Acute 1

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

新产品

从最新的版本中选择一种:

分析证书(COA)

Lot/Batch Number

没有发现合适的版本?

如果您需要特殊版本,可通过批号或批次号查找具体证书。

已有该产品?

在文件库中查找您最近购买产品的文档。

访问文档库

Catalyzed Dehydrogenative Coupling of Primary Alcohols with Water, Methanol, or Amines
Zweifel, T., et al
Angewandte Chemie (International Edition in English), 49, 2009-2009 (2009)
Electromeric rhodium radical complexes.
Florian Frank Puschmann et al.
Angewandte Chemie (International ed. in English), 49(2), 385-389 (2009-12-04)
Torsten Büttner et al.
Chemical communications (Cambridge, England), 24(24), 2820-2821 (2004-12-16)
A combination of the rigid bis(5H-dibenzo[a,d]cyclohepten-5-yl)amine (trop(2)NH) and 5-amino-5H-dibenzo[a,d]cycloheptene (tropNH(2)) ligand allowed the synthesis of the stable pentacoordinated 18 electron amine olefin rhodium(i) complex [Rh(trop(2)NH)(tropNH(2))]O(3)SCF(3)(); this complex can be cleanly deprotonated [pK(a)(DMSO) = 20.6(1)] to the corresponding amide [Rh(trop(2)N)(tropNH(2))](6) which
Chiral Rhodium(I) and Iridium(I) Amino-Olefin Complexes:? pKa, N-H Bond Dissociation Energy, and Catalytic Transfer Hydrogenation
Maire, P., et al.
Organometallics, 24, 3207-3218 (2005)
Ethanol as hydrogen donor: highly efficient transfer hydrogenations with rhodium(I) amides.
Theo Zweifel et al.
Angewandte Chemie (International ed. in English), 47(17), 3245-3249 (2008-03-19)

我们的科学家团队拥有各种研究领域经验,包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系技术服务部门