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Merck
CN

744050

Sigma-Aldrich

(二氟甲基)三甲基硅烷

≥98.0% (GC)

别名:

(Trimethylsilyl)difluoromethane, Trimethyl(difluoromethyl)silane

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About This Item

线性分子式:
(CH3)3SiCHF2
CAS号:
分子量:
124.20
Beilstein:
2423974
MDL编号:
UNSPSC代码:
12352101
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

≥98.0% (GC)

形式

liquid

SMILES字符串

C[Si](C)(C)C(F)F

InChI

1S/C4H10F2Si/c1-7(2,3)4(5)6/h4H,1-3H3

InChI key

OOKFLLNDYNWCHK-UHFFFAOYSA-N

象形图

Flame

警示用语:

Danger

危险声明

危险分类

Flam. Liq. 2

WGK

WGK 3

闪点(°F)

1.4 °F

闪点(°C)

-17 °C

法规信息

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Yanchuan Zhao et al.
Organic letters, 13(19), 5342-5345 (2011-09-14)
Since 1995, Me(3)SiCF(2)H has been widely believed to be an inefficient difluoromethylating agent, which requires harsh reaction conditions to cleave its rather inert Si-CF(2)H bond. However, it has now been found that, by using a proper Lewis base activator, Me(3)SiCF(2)H
Marc Tordeux et al.
Magnetic resonance in chemistry : MRC, 42(8), 700-703 (2004-07-13)
Isotope effects on fluorine chemical shifts induced by heteroatoms bonded covalently to a carbon atom bearing fluorine atoms were studied. For each compound, the isotope-induced chemical shifts 2delta19F(X) through two bonds were measured for the heteroatom (X = 29/28Si, 30/28Si

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The major research interests of Prof. Jinbo Hu's lab include the development of new fluorination reagents and reactions, especially the difluoromethylation, difluoromethylenation, and monofluoromethylation methods.

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