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Merck
CN
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安全信息

743003

Sigma-Aldrich

2-过氧化丁酮

technical

别名:

甲基乙基酮过氧化物, 过氧化甲乙酮

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About This Item

线性分子式:
C2H5C(OOH)(CH3)OOC(OOH)(CH3)C2H5
CAS号:
1338-23-4
分子量:
210.22
Beilstein:
1759757
MDL编号:
MFCD00042641
UNSPSC代码:
12352120
PubChem化学物质编号:
329765606
NACRES:
NA.22

等级

technical

表单

liquid

包含

2,2,4-trimethyl-1,3-pentanediol-diisobutyrate as stabilizer

反应适用性

reagent type: oxidant

折射率

n20/D 1.432

密度

1.053 g/mL at 20 °C (lit.)

官能团

hydroperoxide
peroxide

储存温度

2-8°C

SMILES字符串

CCC(C)(OO)OOC(C)(CC)OO

InChI

1S/C8H18O6/c1-5-7(3,11-9)13-14-8(4,6-2)12-10/h9-10H,5-6H2,1-4H3

InChI key

WFUGQJXVXHBTEM-UHFFFAOYSA-N

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应用

反应物用于：
  • 过氧化甲乙酮绝热失控反应的研究
  • 磨料溶出方波伏安法测定考古玻璃中的金属离子
  • 过氧化氢和过氧化氢清除物质的光子发射成像
  • 亚磷酰胺法合成寡核苷酸
  • 核苷亚磷酸酯氧化成磷酸盐
  • 人血浆谷胱甘肽过氧化物酶作为氢过氧化物酶还原催化剂的比较

乙醇-水体系中固定化血红蛋白直接电化学催化的分析物

警示用语：

Danger

危险分类

Acute Tox. 4 Oral - Flam. Liq. 3 - Org. Perox. D - Skin Corr. 1B

储存分类代码

5.2 - Organic peroxides and self-reacting hazardous materials

WGK

WGK 1

闪点(°F)

132.8 °F - closed cup

闪点(°C)

56 °C - closed cup

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCF7634
BCCB0718
BCBV4363
BCBV2664
BCBG4416V

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F T Fraunfelder et al.
American journal of ophthalmology, 110(6), 635-640 (1990-12-15)
Methyl ethyl ketone peroxide is a commonly used catalyst in various industries. We studied 19 eyes with a single exposure to methyl ethyl ketone peroxide that developed clinical patterns of mild injury, moderate injury, severe injury, or delayed keratitis. Delayed
M Ando et al.
Toxicology and applied pharmacology, 81(3 Pt 1), 517-524 (1985-12-01)
Some new aspects of damage to cytochrome P-450 peroxidase activities by a toxic peroxide were investigated. Methyl ethyl ketone peroxide (MEKP) damage to cytochrome P-450 and inhibition of cytochrome P-450-mediated peroxidase activities were studied. In vivo, hepatic microsomal NADH- and
Oesophageal stenosis in a child caused by ingestion of methyl ethyl ketone peroxide.
A Prez-Martnez et al.
European journal of pediatrics, 156(12), 976-977 (1998-02-07)
M N Bozdemir et al.
Human & experimental toxicology, 30(12), 2002-2006 (2011-04-22)
Although ingestion of methyl ethyl ketone peroxide (MEKP) is rare, it carries a high risk of morbidity and mortality. This paper reports the first such case from Turkey in which a 70-year-old man unintentionally ingested MEKP in his kitchen. The
Jing Zhang et al.
Journal of hazardous materials, 181(1-3), 1024-1030 (2010-06-18)
Methyl ethyl ketone peroxide (MEKPO) is widely used in polymer industry. It is highly sensitive to heat, friction, shock, flame or other sources of ignition, causing risks in production, storage and transportation. In this article, MEKPO is synthesized at a
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