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Merck
CN

741248

双三苯基膦二氯化钯

solid

别名:

PdCl2(PPh3)2, 三苯基膦氯化钯, 二氯二(三苯基膦)钯(II)

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关于此项目

线性分子式:
[(C6H5)3P]2PdCl2
化学文摘社编号:
13965-03-2
分子量:
701.90
NACRES:
NA.22
PubChem Substance ID:
329765477
UNSPSC Code:
12161600
EC Number:
237-744-2
MDL number:
MFCD00009593
Beilstein/REAXYS Number:
4935975

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产品名称

双三苯基膦二氯化钯,

InChI

1S/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2

SMILES string

Cl[Pd]Cl.c1(P(c2ccccc2)c3ccccc3)ccccc1.c4(P(c5ccccc5)c6ccccc6)ccccc4

InChI key

YNHIGQDRGKUECZ-UHFFFAOYSA-L

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium
reagent type: ligand

functional group

phosphine

Quality Level

100

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相关类别

Application

钯催化交叉偶联反应应用指南
二（三苯基膦）二氯化钯 (II) 通常用作通过 斯蒂尔偶联合成共轭聚合物的催化剂 。它也适用于其他偶联反应，如铃木 和 Sonogashira-偶联反应

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H317,H413

Hazard Classifications

Aquatic Chronic 4 - Skin Sens. 1A

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCZ0384
MKCX6018
MKCX2497
MKCW6286
MKCT5715

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Influence of catalytic systems in Stille polymerization on the electrochromic performance of diketopyrrolopyrrole-based conjugated polymers.
Neo WT, et al.
Materials Chemistry Frontiers. (2018)
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Various tetrasubstituted pyrroles/pyrazoles have been prepared from nitro-substituted 1,3-enynes with aromatic amines/hydrazines via a copper-catalyzed cascade aza-Michael addition, cyclization and aromatization at room temperature. This protocol is also effective for the synthesis of tetrasubstituted pyrazoles in high yields.
Hiroaki Imoto et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(34), 12105-12111 (2015-07-17)
Aggregation-induced emission (AIE)-active maleimide dyes, namely, 2-p-toluidino-N-p-tolylmaleimide, 3-phenyl-2-toluidino-N-p-tolylmaleimide, 2-p-thiocresyl-3-p-toluidino-N-p-tolylmaleimide, and 2,3-dithiocresyl-N-arylmaleimides, were synthesized by facile synthetic procedures. The dyes show intense emission in the solid state, and emission colors were controlled from green (λmax =527 nm) to orange (λmax =609 nm) by

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