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表单
liquid
质量水平
反应适用性
reagent type: reductant
折射率
n20/D 1.526
密度
0.887 g/mL at 25 °C
储存温度
2-8°C
SMILES字符串
CC[Si](CC)(CC)[SiH]([Si](CC)(CC)CC)[Si](CC)(CC)CC
InChI
1S/C18H46Si4/c1-10-20(11-2,12-3)19(21(13-4,14-5)15-6)22(16-7,17-8)18-9/h19H,10-18H2,1-9H3
InChI key
WNGZMQFMMHZKBG-UHFFFAOYSA-N
应用
Tris(triethylsilyl)silane can be incorporated as a directing group for various regio- and stereo-selective reactions. Hydrogen abstraction from tris(triethylsilyl)silane yields highly stable silyl radical.
Tris(triethylsilyl)silane can be used as a hydrogen atom donor reagent in chemical synthesis due to its weak Si-H bond. Hydrogen abstraction from tris(triethylsilyl)silane yields a highly stable silyl radical.
It can be used as a reagent:
It can be used as a reagent:
- In the radical coupling reaction to generate C-C bonds from alkyl-halogen compounds using iridium and nickel catalysts.
- To synthesize α-arylated product via cross-electrophile coupling reaction between α-chloro carbonyl and aryl bromide in the presence of nickel and iridium catalysts.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Synthesis of ?-Hydroxy-?-haloesters through Super Silyl Ester Directed Syn-Selective Aldol Reaction.
Oda S and Yamamoto H
Organic Letters, 15(23), 6030-6033 (2013)
Generation of Organolithium Compounds bearing Super Silyl Ester and their Application to Matteson Rearrangement.
Oda S and Yamamoto H
Angewandte Chemie (International Edition in English), 125(31), 8323-8326 (2013)
Selective Michael Reaction Controlled by Supersilyl Protecting Group.
Izumiseki A and Yamamoto H
Angewandte Chemie (International Edition in English), 127(30), 8821-8823 (2015)
Tiffany Q Chen et al.
Angewandte Chemie (International ed. in English), 58(41), 14584-14588 (2019-08-15)
Here, we demonstrate that a metallaphotoredox-catalyzed cross-electrophile coupling mechanism provides a unified method for the α-arylation of diverse activated alkyl chlorides, including α-chloroketones, α-chloroesters, α-chloroamides, α-chlorocarboxylic acids, and benzylic chlorides. This strategy, which is effective for a wide variety of
Jonathan D Bell et al.
Chemical Society reviews, 50(17), 9540-9685 (2021-07-27)
Photoredox chemistry with organic or transition metal agents has been reviewed in earlier years, but such is the pace of progress that we will overlap very little with earlier comprehensive reviews. This review first presents an overview of the area
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