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形式
solid
反应适用性
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
mp
87-92 °C
储存温度
2-8°C
SMILES字符串
[Pd].C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C4CCC(CC4)P(C5CCCCC5)C6CCCCC6
InChI
1S/2C18H33P.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h2*16-18H,1-15H2;
InChI key
JGBZTJWQMWZVNX-UHFFFAOYSA-N
应用
Bis(tricyclohexylphosphine)palladium(0) [Pd(PCy3)2] is a general palladium precatalyst that can be used to catalyze various reactions such as thioesterification of alkynes, alumination of unactivated arenes, direct arylation polycondensation and intramolecular alkane arylation adjacent to amides and sulfonamides.
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Direct arylation polycondensation for synthesis of optoelectronic materials.
Kuwabara J.
Polymer Journal (2018)
Room temperature catalytic carbon?hydrogen bond alumination of unactivated arenes: mechanism and selectivity.
Hooper T, et al.
Chemical Science, 9, 5435-5440 (2018)
Investigation of the mechanism of C (sp3)? H bond cleavage in Pd (0)-catalyzed intramolecular alkane arylation adjacent to amides and sulfonamides.
Rousseaux S, et al.
Journal of the American Chemical Society, 132(31), 10692-10705 (2010)
Palladium-catalyzed thioesterification of alkynes with O-methyl S-phenyl thiocarbonate.
Hua R, et al.
Journal of the American Chemical Society, 123(12), 2899-2900 (2001)
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