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Merck
CN

736015

Sigma-Aldrich

D149 染料

98% (HPLC)

别名:

5-[[4-[4-(2,2-二苯基乙烯基)苯基]-1,2,3,3A,4,8B-六氢环戊烯并[B]吲哚-7-基]亚甲基]-2-(3-乙基-4-氧代-2-硫酮-5-噻唑亚基)-4-氧代-3-噻唑烷乙酸, Indoline dye D149, 紫色染料

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About This Item

经验公式(希尔记法):
C42H35N3O4S3
分子量:
741.94
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23

质量水平

方案

98% (HPLC)

表单

solid

mp

284-289 °C

λmax

531 nm

SMILES字符串

CCN1C(=S)SC(\C1=O)=C2\SC(=C/c3ccc4N(C5CCCC5c4c3)c6ccc(cc6)\C=C(\c7ccccc7)c8ccccc8)\C(=O)N2CC(O)=O

InChI

1S/C42H35N3O4S3/c1-2-43-40(49)38(52-42(43)50)41-44(25-37(46)47)39(48)36(51-41)24-27-18-21-35-33(23-27)31-14-9-15-34(31)45(35)30-19-16-26(17-20-30)22-32(28-10-5-3-6-11-28)29-12-7-4-8-13-29/h3-8,10-13,16-24,31,34H,2,9,14-15,25H2,1H3,(H,46,47)/b36-24-,41-38+

InChI key

OZFUEQNYOBIXTB-SJIUXOFISA-N

一般描述

D149染料是一种吲哚啉染料,消光系数达68700 mol-1cm。它具有高光电转化效率,可用作敏化剂。

应用

D149染料可作为有机染料,增强染料敏化太阳能电池 (DSSC) 的光吸收。
光敏红紫染料具有优异的光电转换效率,是一种无金属染料。
开路电压-Voc(mV)-708.6
Jsc(mA/cm2)= 14.05
填充系数 − ff − 0.67
效率 − η − 6.67

细胞面积:0.25 cm2 (0.5 cm × 0.5 cm)
TiO2 厚度:5 μm
FTO 玻璃: AGC Fabritec A11DU80
TiO2: 丝网印刷(Catalysts & Chemicals IND.有限公司。
PST−18NR/400C (4/1 混合浆)
电解质;0.1 M LiI;0.05 M I2;0.6 M 二甲基丙基咪唑
碘化物;0.05 M 丁基吡啶,溶于 3-甲氧基丙腈中
光源:AM1.5 1sun
反电极:Pt/Cr 混彩玻璃
染料吸附:30 °C/3 小时内。(t-BuOH/乙腈溶液)

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Characterization of solid-state dye-sensitized solar cells utilizing high absorption coefficient metal-free organic dyes
Howie WH, et al.
Journal of the American Chemical Society, 130(4), 1367-1375 (2008)
Tina Caskey et al.
Journal of AOAC International (2019-08-24)
Background: The U.S. Pharmacopeia (USP) established microbiological procedures to evaluate nonsterile products and nutritional and dietary supplements for objectionable microorganisms of concern in the industry. A rapid method has been developed to detect the presence of microorganisms based on real-time
High-conversion-efficiency organic dye-sensitized solar cells with a novel indoline dye
Ito S, et al.
Chemical Communications (Cambridge, England), 126(41), 5194-5196 (2008)
Tamotsu Horiuchi et al.
Journal of the American Chemical Society, 126(39), 12218-12219 (2004-09-30)
We now report metal-free organic dyes having a new type of indoline structure, which exhibits high efficiencies in dye-sensitized solar cells. The solar energy to current conversion efficiencies with the new indoline dye was 6.51%. Under the same conditions, the
High-efficiency organic-dye-sensitized solar cells controlled by nanocrystalline-TiO2 electrode thickness
Ito S, et al.
Advanced Materials, 18(9), 1202-1205 (2006)

商品

Dye-sensitized solar cells (DSCs) are 3rd generation solar cells combining the promise of high efficiency with low production costs.

While dye sensitization as the basis for color photography has been accepted for a very long time,1 attempts to use this principle for the conversion of solar light to electricity generally had resulted only in very low photocurrents, below 100 nA/cm

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