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Merck
CN

735906

Sigma-Aldrich

溴化铜

AnhydroBeads, -10 mesh, 99.99% trace metals basis

别名:

一溴化铜

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About This Item

线性分子式:
CuBr
CAS号:
分子量:
143.45
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23

产品线

AnhydroBeads

质量水平

检测方案

99.99% trace metals basis

形式

beads

杂质

≤150.0 ppm Trace Metal Analysis

粒径

-10 mesh

mp

504 °C (lit.)

密度

4.71 g/mL at 25 °C (lit.)

应用

battery manufacturing

SMILES字符串

[Cu]Br

InChI

1S/BrH.Cu/h1H;/q;+1/p-1

InChI key

NKNDPYCGAZPOFS-UHFFFAOYSA-M

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一般描述

Cuprous bromide may be prepared by the reduction of cupric bromide or CuSO4-NaBr. In the molten state, it is grayish brown /greenish brown in color.

应用

Some reported applications of copper bromide are:
  • catalyst in cross coupling reactions.
  • co-catalyst in Sonogashira coupling.
  • Lewis acid in enantioselective addition of alkynes.
  • reducing agent, when complexed by three molecules of pyridine initiators for the controlled polymerization of styrene, methyl acrylate and methyl methacrylate.

Reductive homocoupling of α-bromo- α- chlorocarboxylates to dimethyl α, α′ dichlorosuccinate derivatives in presence of CuBr/LiOCH3 in methanol has been reported.

法律信息

AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC

警示用语:

Danger

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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Study on atom transfer radical polymerization initiated by p-nitrophenyl initiator and synthesis of amino end-functionalized polymers thereof
Qu, T.; Cai, W.; Fu, Z.; Shi, Y.
Macromolecular Research, 18(7), 623-629 (2010)
Denissova I and Barriault L
Handbook of Reagents for Organic Synthesis null
Shengtong Sun et al.
The journal of physical chemistry. A, 114(32), 8331-8336 (2010-08-13)
A designed ligand-accelerated Cu(I)-catalyzed cycloaddition (CuAAC) reaction was monitored for the first time by real time infrared analysis technique based on ATR-FTIR principles. Principal components analysis (PCA) and two-dimensional correlation spectroscopy (2Dcos) results showed that the consumption of alkyne and
Denissova I and Barriault L et al.
Handbook of Reagents for Organic Synthesis null
B Podobnik et al.
Bioconjugate chemistry, 26(3), 452-459 (2015-01-30)
The covalent attachment of poly(ethylene glycol) (PEG) to therapeutic proteins is a commonly used approach for extending in vivo half-lives. A potential limitation of this PEGylation strategy is the adverse effect of PEG on conjugate viscosity. Interferon-alpha (IFN) was conjugated

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