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Merck
CN

734519

Gadolinium-doped ceria

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<0.5 μm particle size, powder, contains 10 mol % gadolinium as dopant

别名:

Cerium(IV) oxide-gadolinium doped, Cerium-gadolinium oxide, GDC-10, Gadolinium doped ceria

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关于此项目

经验公式(希尔记法):
CeO2
分子量:
172.11
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.23
MDL number:
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产品名称

钆掺杂的氧化铈(IV), <0.5 μm particle size, powder, contains 10 mol % gadolinium as dopant

form

powder

SMILES string

[Gd].O=[Ce]=O

InChI key

ZBPTVGKVCOMWPA-UHFFFAOYSA-N

InChI

1S/Ce.Gd.2O

contains

10 mol % gadolinium as dopant

composition

Gd0.1Ce0.9O1.95

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Design for Energy Efficiency
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surface area

10.0-14.0 m2/g

particle size

0.10-0.50 μm (d50)
<0.5 μm

bulk density

1.739 g/mL

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Quality Level

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Application

Gadolinium doped ceria (GDC) may be used as an intermediate temperature electrolyte for solid oxide fuel cells (SOFCs) at elevated temperatures.

General description

Cerium(IV) oxide-gadolinium doped powder (10 mol% gadolinium doped) (GDC-10) is an electrolytic material with high oxygen-ion conductivity, which operates at low temperatures. It can be prepared by a variety of methods such as sol-gel, wet chemical process, co-precipitation, hydrothermal and other combustion routes.
Gadolinium doped ceria may be prepared by cation complexation sol-gel technique. XRD, specific surface area, morphology has been described in a study. Higher oxygen ion conductivity of GDC over zirconia-based materials makes it a preferable choice for some components of SOFCs.
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存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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分析证书(COA)

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Chemically-induced stresses in gadolinium-doped ceria solid oxide fuel cell electrolytes
Atkinson A
Solid State Ionics, 95(3-4), 249-258 (1997)
Thermal expansion of Gd-doped ceria and reduced ceria.
Hayashi H, et al.
Solid State Ionics, 132(3), 227-233 (2000)
Synthesis and properties of Gadolinium-doped ceria solid solutions for IT-SOFC electrolytes
Fuentes RO and Baker RT
International Journal of Hydrogen Energy, 33(13), 3480-3484 (2008)
Microstructure and Grain-Boundary Effect on Electrical Properties of Gadolinium-Doped Ceria.
Zhou XD, et al.
Journal of the American Ceramic Society. American Ceramic Society, 85(7), 1757-1762 (2002)

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