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方案
>99%
表单
solid
mp
211-214 °C
λmax
1.8732 at 274 nm
吸附
0.25821 at 394 nm
0.61112 at 416 nm
0.84016 at 442 nm
荧光
λex 435 nm; λem 475 nm (concentration = 0.00002 mg/mL)
轨道能量
HOMO 5.6 eV (CV)
LUMO 2.9 eV (CV)
SMILES字符串
CC(C)[Si](C#Cc1c2ccccc2c(C#C[Si](C(C)C)(C(C)C)C(C)C)c3ccccc13)(C(C)C)C(C)C
InChI
1S/C36H50Si2/c1-25(2)37(26(3)4,27(5)6)23-21-35-31-17-13-15-19-33(31)36(34-20-16-14-18-32(34)35)22-24-38(28(7)8,29(9)10)30(11)12/h13-20,25-30H,1-12H3
InChI key
FEAZNDXDTUMTIL-UHFFFAOYSA-N
一般描述
9,10-Bis[(triisopropylsilyl)ethynyl]anthracene is a novel organic photocatalyst.
应用
The photocatalyst may be useful in the affording free radicals during polymerization via irradiated photoredox catalysis.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Organic photocatalyst for polymerization reactions: 9, 10-bis [(triisopropylsilyl) ethynyl] anthracene.
Tehfe, Mohamad-Ali, et al.
ACS Macro Letters null
Organic photocatalyst for polymerization reactions: 9, 10-bis [(triisopropylsilyl) ethynyl] anthracene.
Tehfe, Mohamad-Ali, et al.
ACS Macro Letters, 198-203 null
Intermolecular Effects on the Hole States of Triisopropylsilylethynyl-Substituted Oligoacenes
Griffith, O. L.; Jones, A. G.; Anthony, J. E.; Lichtenberger, D. L.
The Journal of Physical Chemistry C, 114, 13838-13838 (2010)
Jong-Hwa Park et al.
Organic letters, 9(13), 2573-2576 (2007-06-05)
New soluble anthracene derivatives containing thiophene and phenylenevinylene derivatives were synthesized via well-known synthetic routes. TIPS derivatives were added at the 9,10-positions of anthracene for the solubility and crystallinity. Both of the molecules were found to be promising for high
商品
Organic materials in optoelectronic devices like LEDs and solar cells are of significant academic and commercial interest.
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