所有图片(2)
别名:
9,10-Bis{2-[tris(1-methylethyl)silyl]ethynyl}anthracene, TIPS-anthracene
经验公式（希尔记法）:
C36H50Si2
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检测方案
>99%
形式
solid
mp
211-214 °C
λmax
1.8732 at 274 nm
吸光度
0.25821 at 394 nm
0.61112 at 416 nm
0.84016 at 442 nm
荧光
λex 435 nm; λem 475 nm (concentration = 0.00002 mg/mL)
轨道能量
HOMO 5.6 eV (CV)
LUMO 2.9 eV (CV)
SMILES字符串
CC(C)[Si](C#Cc1c2ccccc2c(C#C[Si](C(C)C)(C(C)C)C(C)C)c3ccccc13)(C(C)C)C(C)C
InChI
1S/C36H50Si2/c1-25(2)37(26(3)4,27(5)6)23-21-35-31-17-13-15-19-33(31)36(34-20-16-14-18-32(34)35)22-24-38(28(7)8,29(9)10)30(11)12/h13-20,25-30H,1-12H3
InChI key
FEAZNDXDTUMTIL-UHFFFAOYSA-N
一般描述
9,10-Bis[(triisopropylsilyl)ethynyl]anthracene is a novel organic photocatalyst.
应用
The photocatalyst may be useful in the affording free radicals during polymerization via irradiated photoredox catalysis.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Organic photocatalyst for polymerization reactions: 9, 10-bis [(triisopropylsilyl) ethynyl] anthracene.
Tehfe, Mohamad-Ali, et al.
ACS Macro Letters null
Jong-Hwa Park et al.
Organic letters, 9(13), 2573-2576 (2007-06-05)
New soluble anthracene derivatives containing thiophene and phenylenevinylene derivatives were synthesized via well-known synthetic routes. TIPS derivatives were added at the 9,10-positions of anthracene for the solubility and crystallinity. Both of the molecules were found to be promising for high
Organic photocatalyst for polymerization reactions: 9, 10-bis [(triisopropylsilyl) ethynyl] anthracene.
Tehfe, Mohamad-Ali, et al.
ACS Macro Letters, 198-203 null
Intermolecular Effects on the Hole States of Triisopropylsilylethynyl-Substituted Oligoacenes
Griffith, O. L.; Jones, A. G.; Anthony, J. E.; Lichtenberger, D. L.
The Journal of Physical Chemistry C, 114, 13838-13838 (2010)
商品
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