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730297

Sigma-Aldrich

TEMPO甲基丙烯酸甲酯

97%

别名:

4-氰基苯二硫代碳酸－1－氰基－1－甲基乙基酯, PTMA 单体

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1 KIT
¥4,429.37

¥4,429.37

预计发货时间2025年6月05日详情

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1 KIT
¥4,429.37

About This Item

经验公式（希尔记法）:
C13H22NO3
CAS号:
15051-46-4
分子量:
240.32
MDL编号:
MFCD17677357
UNSPSC代码:
12162002
PubChem化学物质编号:
329764552
NACRES:
NA.23

¥4,429.37

预计发货时间2025年6月05日详情

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获取大包装报价

方案

97%

表单

powder

mp

86-90 °C

储存温度

2-8°C

SMILES字符串

CC(=C)C(=O)OC1CC(C)(C)N([O])C(C)(C)C1

InChI

1S/C13H22NO3/c1-9(2)11(15)17-10-7-12(3,4)14(16)13(5,6)8-10/h10H,1,7-8H2,2-6H3

InChI key

BTWSPOZXDCFMLX-UHFFFAOYSA-N

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NanoFabTx™ PEGylated nanoparticle formulation screening kit

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NanoFabTx™ PEGylated nanoparticle formulation screening kit

NanoFabTx™ PEG-PLGA drug formulation screening kit for synthesis of PEGylated nanoparticles

917796

NanoFabTx™ PEG-PLGA drug formulation screening kit

NanoFabTx™ PEG-PCL drug formulation screening kit for synthesis of PEGylated nanoparticles

918881

NanoFabTx™ PEG-PCL drug formulation screening kit

NanoFabTx™ PLA-nano for synthesis of 100 and 200 nm particles

918075

NanoFabTx™ PLA-nano

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

description

Kit components :
PEGPLGA-50L (912808-500mg)
PEGPLGA-75L (913049-500mg)
PEGPLA-L (913308-500mg)
PEGPCL-H (912549-500mg)
Stabilizer - P (913448-10g)

description

Drug loading screening kit, for synthesis of PEGylated PLGA nanoparticles, Kit components :
PEGPLGA-50L(912808-500mg)
PEGPLGA-75L(913049-500mg)
PEGPLGA-50H (915955-500mg)
PEGPLGA-75H (915718-500mg)
Stabilizer-Nano (907766-5g)

description

Drug loading screening kit, for synthesis of PEGylated PCL nanoparticles, Kit components :
PEGPCL-L(915203-500mg)
PEGPCL-H(912549-500mg)
PEGPCL-UH (917788-500mg)
Stabilizer-Nano (907766-5g)

description

-

application(s)

advanced drug delivery

application(s)

advanced drug delivery

application(s)

advanced drug delivery

application(s)

advanced drug delivery

一般描述

TEMPO 甲基丙烯酸酯（4-甲基丙烯酰氧基-2,2,6,6-四甲基哌啶-1-氧基） 经历阴离子分散聚合得到含有 2,2,6,6-四甲基哌啶-1-氧基（TEMPO）自由基的纳米聚合物粒子。[1]

应用

TEMPO 甲基丙烯酸酯（4-甲基丙烯酰氧基-2,2,6,6-四甲基哌啶-1-氧基）可用作苯乙烯聚合的反自由基。[2]
稳定的氮氧自由基有助于控制活性自由基聚合，具有交联或正交聚合的甲基丙烯酸酯功能。

象形图

Exclamation markEnvironment
GHS07,GHS09

警示用语：

Warning

危险声明

H317,H411

危险分类

Aquatic Chronic 2 - Skin Sens. 1

储存分类代码

11 - Combustible Solids

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

    • 历史批次信息供参考:

    分析证书(COA)

    Lot/Batch Number
    MKCP9189
    MKCP8329
    MKCN3298
    MKCN0233
    MKCC6925

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    如果您需要特殊版本，可通过批号或批次号查找具体证书。

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    在文件库中查找您最近购买产品的文档。

    访问文档库

    Magnetic force microscopic images of nanometer-sized polyradical particles.
    Michinobu T, et al.
    Polymer Journal, 35(1), 71-75 (2003)
    Nakahara, K.; Iwasa, S.; Satoh, M.; Morioka, Y.; Iriyama, J.; Suguro, M.; Hasegawa, E.
    Chemical Physics Letters, 359, 351-351 (2002)
    Controlled radical polymerization of styrene in the presence of a polymerizable nitroxide compound.
    Li C, et al.
    Macromolecules, 32(21), 7012-7014 (1999)
    Battery-inspired, nonvolatile, and rewritable memory architecture: a radical polymer-based organic device.
    Yasunori Yonekuta et al.
    Journal of the American Chemical Society, 129(46), 14128-14129 (2007-10-30)

    商品

    Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

    Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

    TEMPO催化氧化

    TEMPO（2,2,6,6-四甲基哌啶氧基或2,2,6,6-四甲基哌啶1-氧基）及其衍生物在有机氧化反应催化剂中可以作为稳定的硝酰基使用。TEMPO由Lebedev和Kazarnovskii于1960年发现，其具有的稳定自由基性质得益于其庞大的取代基团阻碍了自由基与其他分子之间发生反应。

    Micro Review of RAFT Polymerization

    Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

    实验方案

    Concepts and Tools for RAFT Polymerization

    We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

    Typical Procedures for Polymerizing via RAFT

    We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

    Polymerizing via ATRP

    Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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