726834
(S)-苯基环氧乙烷
ChiPros®, produced by BASF, 98%
别名:
(S)-氧化苯乙烯, (S)-环氧苯乙烷
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关于此项目
经验公式（希尔记法）:
C8H8O
化学文摘社编号:
分子量:
120.15
PubChem Substance ID:
UNSPSC Code:
12352005
Beilstein/REAXYS Number:
3587977
MDL number:
Assay:
≥97.5% (GC), 98%
Form:
liquid
SMILES string
C1O[C@H]1c2ccccc2
InChI
1S/C8H8O/c1-2-4-7(5-3-1)8-6-9-8/h1-5,8H,6H2/t8-/m1/s1
InChI key
AWMVMTVKBNGEAK-MRVPVSSYSA-N
assay
≥97.5% (GC), 98%
form
liquid
optical purity
enantiomeric excess: ≥97.5%
bp
192-194 °C (lit.)
density
1.051 g/mL at 20 °C (lit.)
Legal Information
ChiPros is a registered trademark of BASF SE
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Aquatic Chronic 2 - Carc. 1B - Eye Irrit. 2 - Skin Irrit. 2
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
174.2 °F - closed cup
flash_point_c
79 °C - closed cup
法规信息
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Michael Kotik et al.
Journal of biotechnology, 156(1), 1-10 (2011-08-23)
We performed a laboratory evolution study with the epoxide hydrolase from Aspergillus niger M200. This enzyme exhibits no enantioconvergence with the substrates styrene oxide or para-chlorostyrene oxide, i.e. racemic vicinal diols are produced from the racemic substrates. After saturation mutagenesis
Rainer Gross et al.
Biotechnology and bioengineering, 110(2), 424-436 (2012-08-14)
This study evaluates the technical feasibility of biofilm-based biotransformations at an industrial scale by theoretically designing a process employing membrane fiber modules as being used in the chemical industry and compares the respective process parameters to classical stirred-tank studies. To
Daniel Kuhn et al.
Journal of industrial microbiology & biotechnology, 39(8), 1125-1133 (2012-04-25)
Selection of the ideal microbe is crucial for whole-cell biotransformations, especially if the target reaction intensively interacts with host cell functions. Asymmetric styrene epoxidation is an example of a reaction which is strongly dependent on the host cell owing to
Wen-Jing Chen et al.
Journal of biotechnology, 162(2-3), 183-190 (2012-09-22)
A comparative study was made of Mung bean epoxide hydrolases-catalyzed asymmetric hydrolysis of styrene oxide to (R)-1-phenyl-1,2-ethanediol in an n-hexane/buffer biphasic system containing various hydrophilic ionic liquids (ILs). Compared to the n-hexane/buffer biphasic system alone, addition of a small amount
Jung-Hee Woo et al.
Biotechnology letters, 35(4), 599-606 (2012-12-18)
A novel epoxide hydrolase (EHase) from polycyclic aromatic hydrocarbon (PAH)-degrading bacteria was identified and characterized. EHase activity was identified in four strains of PAH-degrading bacteria isolated from commercial gasoline and oil-contaminated sediment based on their growth on styrene oxide and
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