推荐产品
等级
produced by BASF
质量水平
蒸汽压
0.5 mmHg ( 20 °C)
方案
≥99.0% (GC)
≥99.0%
表单
liquid
光学纯度
enantiomeric excess: ≥98.0%
折射率
n20/D 1.526 (lit.)
沸点
187-189 °C (lit.)
密度
0.952 g/mL at 20 °C (lit.)
官能团
amine
phenyl
SMILES字符串
C[C@@H](N)c1ccccc1
InChI
1S/C8H11N/c1-7(9)8-5-3-2-4-6-8/h2-7H,9H2,1H3/t7-/m1/s1
InChI key
RQEUFEKYXDPUSK-SSDOTTSWSA-N
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一般描述
(R)-(+)-α-Methylbenzylamine is a chiral amine.
应用
(R)-(+)-α-Methylbenzylamine may be used as a substrate to synthesize:
- (S)-α-amino phosphonates
- N-{(S)-[cyclohexan-(S)-2-ol]}-(R)-α-methylbenzyl amine and N-{(R)-[cyclohexan-(R)-2-ol]}-(R)-α-methylbenzyl amine
- R-α-aminonitriles
法律信息
ChiPros is a registered trademark of BASF SE
警示用语:
Danger
危险声明
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 1
闪点(°F)
158.0 °F - closed cup
闪点(°C)
70 °C - closed cup
Lithium perchlorate/diethylether catalyzed aminophosphonation of aldehydes.
Tetrahedron Letters, 39(37), 6729-6732 (1998)
New enantiomerically pure aminoalcohols from (R)-a-methylbenzylamine and cyclohexene oxide.
Tetrahedron Asymmetry, 7(3), 843-850 (1996)
ChiPros Chiral Amines
Aldrich Chemfiles, 11(1) null
Bioscience, biotechnology, and biochemistry, 72(11), 3030-3033 (2008-11-11)
To produce (S)-alpha-methylbenzylamine (MBA) from acetophenone, recombinant Escherichia coli co-expressing omega-transaminase and acetolactate synthase was used as a whole-cell biocatalyst. The solvent-bridge reaction system increased the yield of the whole-cell reaction by 2.5-fold, and the inhibitory (S)-alpha-MBA produced in the
Organic & biomolecular chemistry, 10(31), 6410-6419 (2012-06-28)
The three-component chiral derivatization protocols have been developed for (1)H, (13)C and (19)F NMR spectroscopic discrimination of chiral diacids by their coordination and self-assembly with optically active (R)-α-methylbenzylamine and 2-formylphenylboronic acid or 3-fluoro-2-formylmethylboronic acid. These protocols yield a mixture of
商品
Chiral amines play an important role in stereoselective organic synthesis. They are used directly as resolving agents, building blocks, or chiral auxiliaries.
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