推荐产品
等级
produced by BASF
质量水平
蒸汽压
0.5 mmHg ( 20 °C)
检测方案
≥99.0% (GC)
≥99.0%
形式
liquid
光学纯度
enantiomeric excess: ≥98.0%
折射率
n20/D 1.526 (lit.)
bp
187-189 °C (lit.)
密度
0.952 g/mL at 20 °C (lit.)
SMILES字符串
C[C@@H](N)c1ccccc1
InChI
1S/C8H11N/c1-7(9)8-5-3-2-4-6-8/h2-7H,9H2,1H3/t7-/m1/s1
InChI key
RQEUFEKYXDPUSK-SSDOTTSWSA-N
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一般描述
(R)-(+)-α-Methylbenzylamine is a chiral amine.
应用
(R)-(+)-α-Methylbenzylamine may be used as a substrate to synthesize:
- (S)-α-amino phosphonates
- N-{(S)-[cyclohexan-(S)-2-ol]}-(R)-α-methylbenzyl amine and N-{(R)-[cyclohexan-(R)-2-ol]}-(R)-α-methylbenzyl amine
- R-α-aminonitriles
法律信息
ChiPros is a registered trademark of BASF SE
警示用语：
Danger
危险声明
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
WGK
WGK 1
闪点(°F)
closed cup
闪点(°C)
closed cup
Lithium perchlorate/diethylether catalyzed aminophosphonation of aldehydes.
Heydari A, et al.
Tetrahedron Letters, 39(37), 6729-6732 (1998)
ChiPros Chiral Amines
Aldrich Chemfiles, 11(1) null
New enantiomerically pure aminoalcohols from (R)-a-methylbenzylamine and cyclohexene oxide.
Barbaro P, et al.
Tetrahedron Asymmetry, 7(3), 843-850 (1996)
Andrew M Kelly et al.
Nature protocols, 3(2), 215-219 (2008-02-16)
A three-component chiral derivatization protocol for determining the enantiopurity of chiral diols by (1)H NMR spectroscopic analysis is described here. The present approach involves the derivatization of 1,2- 1,3- and 1,4-diols with 2-formylphenylboronic acid and enantiopure alpha-methylbenzylamine. This method affords
Bartosz Lewandowski et al.
Chemical communications (Cambridge, England), (47)(47), 6399-6401 (2008-12-03)
Simple chiral aza-crown ethers based on sucrose display high enantioselectivity in complexation of phenylethylammonium chlorides.
商品
Chiral amines play an important role in stereoselective organic synthesis. They are used directly as resolving agents, building blocks, or chiral auxiliaries.
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