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等级
produced by BASF
蒸汽压
0.5 mmHg ( 20 °C)
方案
≥99.0% (GC)
≥99.0%
表单
liquid
光学纯度
enantiomeric excess: ≥99.0%
折射率
n20/D 1.526 (lit.)
沸点
187 °C (lit.)
密度
0.94 g/mL at 25 °C (lit.)
官能团
amine
phenyl
SMILES字符串
C[C@H](N)c1ccccc1
InChI
1S/C8H11N/c1-7(9)8-5-3-2-4-6-8/h2-7H,9H2,1H3/t7-/m0/s1
InChI key
RQEUFEKYXDPUSK-ZETCQYMHSA-N
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应用
- The first example of a diastereoselective thio-Ugi reaction: a new synthetic approach to chiral imidazole derivatives.: This research presents a novel diastereoselective thio-Ugi reaction, enabling the synthesis of chiral imidazole derivatives, which are essential in asymmetric synthesis and pharmaceutical intermediates (Gulevich et al., 2007).
- Synthesis and serotonin receptor affinities of a series of enantiomers of alpha-methyltryptamines: evidence for the binding conformation of tryptamines at serotonin 5-HT1B receptors.: This study investigates the synthesis and serotonin receptor affinities of alpha-methyltryptamine enantiomers, contributing to the understanding of chiral compounds in medicinal chemistry (Nichols et al., 1988).
法律信息
ChiPros is a registered trademark of BASF SE
警示用语：
Danger
危险声明
危险分类
Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Skin Corr. 1B
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 1
闪点(°F)
158.0 °F - closed cup
闪点(°C)
70 °C - closed cup
Bartosz Lewandowski et al.
Chemical communications (Cambridge, England), (47)(47), 6399-6401 (2008-12-03)
Simple chiral aza-crown ethers based on sucrose display high enantioselectivity in complexation of phenylethylammonium chlorides.
Andrew M Kelly et al.
Nature protocols, 3(2), 215-219 (2008-02-16)
A three-component chiral derivatization protocol for determining the enantiopurity of chiral diols by (1)H NMR spectroscopic analysis is described here. The present approach involves the derivatization of 1,2- 1,3- and 1,4-diols with 2-formylphenylboronic acid and enantiopure alpha-methylbenzylamine. This method affords
G Palaprat et al.
The journal of physical chemistry. B, 111(31), 9239-9243 (2007-07-20)
A polydomain cholesteric elastomer was obtained by cross-linking a nematic side-chain polysiloxane in the presence of a chiral dopant. After extraction of the chiral dopant, sorption experiments were performed, by the use of an electronic microbalance, in the presence of
Barry Lygo et al.
Organic & biomolecular chemistry, 10(25), 4968-4976 (2012-05-23)
A short synthetic route to diastereoisomeric atropos dihydro-5H-dibenz[c,e]azepinium salts via reaction of a single enantiomer of (R)-α-methylbenzylamine with a racemic atropos biphenol derivative is described. Compounds prepared via this approach are used to provide strong evidence that structurally related tropos
Antoine Fadel et al.
The Journal of organic chemistry, 72(5), 1780-1784 (2007-01-30)
Enantiomerically pure (R)-(+)-pipecolic acid was synthesized in four steps and 42% overall yield starting from dihydropyran and (R)-alpha-methylbenzylamine. A general short strategy is also described for preparing (S)-proline (47.5% overall yield) and derivatives.
商品
Chiral amines play an important role in stereoselective organic synthesis. They are used directly as resolving agents, building blocks, or chiral auxiliaries.
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