检测方案
≥97.0% (CHN)
形式
powder
旋光性
[α]20/D +48±3°, c = 1.4% in chloroform
mp
85-90 °C
SMILES字符串
CC(C)[C@@H]1COC(=N1)c2ccccc2P(c3ccccc3)c4ccccc4
InChI
1S/C24H24NOP/c1-18(2)22-17-26-24(25-22)21-15-9-10-16-23(21)27(19-11-5-3-6-12-19)20-13-7-4-8-14-20/h3-16,18,22H,17H2,1-2H3/t22-/m0/s1
InChI key
OUQSAXROROGQEE-QFIPXVFZSA-N
包装
Bottomless glass bottle. Contents are inside inserted fused cone.
其他说明
可与铱催化剂发生不对称烷基化反应;不对称还原反应的手性配体
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Angewandte Chemie (International Edition in English), 110, 3047-3047 (1998)
Tetrahedron Letters, 38, 8025 -8025 (1997)
相关内容
Andreas Pfaltz has a longstanding interest in the design of chiral ligands for asymmetric catalysis. The semicorrins developed in his group served as the prototype for an important family of nitrogen ligands, the bisoxazolines, which have found widespread use in catalytic asymmetric synthesis.
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