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Merck
CN
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文件

安全信息

719013

Sigma-Aldrich

[(1-哌啶基)甲基]三氟硼酸钾

internal salt

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经验公式（希尔记法）:
C6H13BF3N
CAS号:
1268340-93-7
分子量:
166.98
MDL编号:
MFCD18071160
UNSPSC代码:
12352103
PubChem化学物质编号:
329763622
NACRES:
NA.22

形式

solid

mp

134-149 °C

SMILES字符串

F[B-](F)(F)C[NH+]1CCCCC1

InChI

1S/C6H12BF3N/c8-7(9,10)6-11-4-2-1-3-5-11/h1-6H2/q-1/p+1

InChI key

PFMNVTAJBBIDDU-UHFFFAOYSA-O

应用

(Piperidinium-1-ylmethyl)trifluoroborate can be used as a reagent in the palladium-catalyzed Suzuki-cross coupling reaction with aryl and heteroaryl halides/mesylates to prepare methylpiperidinyl derivatives.
Organotrifluoroborate involved in Suzuki-Miyaura cross-coupling and cross coupling with mesylated phenol derivatives

Organotrifluoroborates as versatile and stable boronic acid surrogates.

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315,H319,H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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Reinvestigation of aminomethyltrifluoroborates and their application in Suzuki- Miyaura cross-coupling reactions
Raushel J, et al.
The Journal of Organic Chemistry, 76(8), 2762-2769 (2011)
Cross-coupling of mesylated phenol derivatives with potassium ammonio-and amidomethyltrifluoroborates
Molander GA and Beaumard F
Organic Letters, 13(5), 1242-1245 (2011)

商品

Potassium Organotrifluoroborates

Bench-stable Potassium Organotrifluoroborates enable diverse C-C bond formation reactions.

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