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主要文件

718165

Sigma-Aldrich

三正辛基膦

97%

别名:

TOP, P(Oct)3

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About This Item

线性分子式:
[CH3(CH2)7]3P
CAS号:
分子量:
370.64
Beilstein:
1776995
EC 号:
MDL编号:
UNSPSC代码:
12352001
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

97%

表单

liquid

反应适用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

折射率

n20/D 1.468 (lit.)

沸点

284-291 °C/50 mmHg (lit.)

密度

0.831 g/mL at 25 °C (lit.)

官能团

phosphine

SMILES字符串

CCCCCCCCP(CCCCCCCC)CCCCCCCC

InChI

1S/C24H51P/c1-4-7-10-13-16-19-22-25(23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3

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一般描述

三辛基膦可作为磷源,用于金属纳米颗粒的合成。[1]

应用

三辛基膦可用于金属纳米晶、块状粉体、箔、线、薄膜向金属磷化物的转化。[2]它还可以作为由醋酸镉和硫中合成硫化镉纳米棒反应的溶剂和稳定剂。[3]

象形图

Corrosion

警示用语:

Danger

危险声明

危险分类

Eye Dam. 1 - Skin Corr. 1B

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 2

闪点(°F)

296.6 °F - closed cup

闪点(°C)

147 °C - closed cup

  • 技术规格说明书

  • 历史批次信息供参考:

    分析证书(COA)

    Lot/Batch Number

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    Trioctylphosphine as both solvent and stabilizer to synthesize CdS nanorods.
    Chen S, et al.
    Nanoscale Research Letters, 4(10), 1159-1159 (2009)
    Trioctylphosphine: a general phosphorus source for the low-temperature conversion of metals into metal phosphides.
    Henkes AE & Schaak RE.
    Chemistry of Materials, 19(17), 4234-4242 (2007)
    Palladium (ii)-complexes of bi-and tri-dentate phosphine ligands: precursor for palladium--phosphorous nanoparticles and activity towards Suzuki--Miyaura coupling
    Rao GK, et al.
    New. J. Chem., 47, 4218-4227 (2023)
    Jaehoon Lim et al.
    Nature materials, 17(1), 42-49 (2017-11-29)
    Chemically synthesized semiconductor quantum dots (QDs) can potentially enable solution-processable laser diodes with a wide range of operational wavelengths, yet demonstrations of lasing from the QDs are still at the laboratory stage. An important challenge-realization of lasing with electrical injection-remains
    Tilman Läppchen et al.
    EJNMMI physics, 7(1), 22-22 (2020-04-24)
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