推荐产品
质量水平
检测方案
85%
形式
powder
mp
>200 °C
储存温度
2-8°C
SMILES字符串
CC(C)(C)O[Ba]OC(C)(C)C
InChI
1S/2C4H9O.Ba/c2*1-4(2,3)5;/h2*1-3H3;/q2*-1;+2
InChI key
SLPLCLDJTNLWPW-UHFFFAOYSA-N
一般描述
Barium tert-butoxide is a Brønsted base catalyst that can be used as a precursor of various barium catalysts like barium aryloxide. It can also be used in the preparation of barium diphenylmethanide, applicable in the organometallic chemistry.
应用
Barium tert-butoxide can be used:
- As a catalyst along with various phenolic ligands in the aldol reactions of amides with aldehydes and ketones.
- To prepare yttrium and copper metal complexes by reacting with Y(thd)3 and Cu(thd)2, where “thd” is 2,2,6,6-tetramethylheptane-3,5-dione.
- As an initiator along with an alkyl lithium in the butadiene copolymerization reaction.
- In the iridium catalyzed allylic alkylation of non-stabilized enolates.
警示用语：
Danger
危险声明
危险分类
Flam. Sol. 2 - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
补充剂危害
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
Iridium-catalyzed diastereo-, enantio-, and regioselective allylic alkylation with prochiral enolates
Hethcox JC, et al.
ACS Catalysis, 6(9), 6207-6213 (2016)
Highly anti-Selective Catalytic Aldol Reactions of Amides with Aldehydes
Saito S and Kobayashi S
Journal of the American Chemical Society, 128(27), 8704-8705 (2006)
Reactivity of mixed-metal BaCu and BaY β-diketonatoalkoxides with lewis bases: Molecular structures of [Ba2Cu (μ3, η2-OCHMeCH2NMe2) 2 (μ, η2-thd) 2 (η2-thd) 2 (PriOH2],[Cu3 (μ3-OBut) 2 (μ-OBut)(η2-thd) 3] and [Ba (η2-thd) 2 (TMEDA) 2]
Labrize F, et al.
Polyhedron, 15(4), 577-589 (1996)
Accessible microstructures of polybutadiene by anionic polymerization
Forens A, et al.
Polymer, 153(4), 103-122 (2018)
Barium tert-butoxide
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2009)
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