714836
一氯化碘 溶液
1 M in acetic acid
别名:
单氯化碘溶液, 氯化碘 溶液
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关于此项目
线性分子式:
ICl
化学文摘社编号:
分子量:
162.36
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587194
Form:
solution
InChI key
QZRGKCOWNLSUDK-UHFFFAOYSA-N
SMILES string
ClI
InChI
1S/ClI/c1-2
form
solution
concentration
1 M in acetic acid
density
1.143 g/mL at 25 °C
Quality Level
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General description
一氯化碘是一种用于芳香族化合物和不饱和化合物的碘化和氯碘化反应的无机试剂。它也可用于裂解碳-金属键。
Application
一氯化碘可用于：
- 作为α-酮砜制备 β碘β-酮砜的试剂。
- 合成3-（4-溴-2-甲基苯基）-4-碘悉尼酮，其可进一步用于制备取代吡唑。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
105.1 °F
flash_point_c
40.6 °C
法规信息
危险化学品
此项目有
Synthesis of α-iodo β-ketosulfones and α-iodo methylsulfones using iodine monochloride
Suryakiran N, et al.
Tetrahedron Letters, 47(26), 4319-4323 (2006)
Iodine monochloride
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2013)
Steric effects on the sydnones reactivity. New sydnones and pyrazoles
Dumitracscu F, et al.
ARKIVOC (Gainesville, FL, United States), 2(26), 80-86 (2002)
K R Siebenlist et al.
Biochemistry, 39(46), 14171-14175 (2000-11-23)
There are conflicting ideas regarding the location of the carboxyl-terminal regions of cross-linked gamma-chain dimers in double-stranded fibrin fibrils. Some investigators believe that the chains are always oriented longitudinally along each fibril strand and traverse the contacting ends of abutting
Ru-Jin Huang et al.
Analytical chemistry, 81(5), 1777-1783 (2009-02-10)
This study concerns the development of a coupled diffusion denuder system capable of separating and quantifying gaseous molecular iodine (I(2)) and two other highly reactive iodine species, ICl and HOI, which are collectively named activated iodine compounds (AIC). Both I(2)
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