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About This Item
经验公式（希尔记法）:
C20H15NO
CAS号:
分子量:
285.34
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
≥96.5% (HPLC)
97%
表单
crystals
光学纯度
enantiomeric excess: ≥98.0%
SMILES字符串
Nc1c(c4c(cc1)cccc4)c2c3c(ccc2O)cccc3
InChI
1S/C20H15NO/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h1-12,22H,21H2
InChI key
HIXQCPGXQVQHJP-UHFFFAOYSA-N
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一般描述
(R)-(+)-2′-Amino-1,1′-binaphthalen-2-ol is a non-symmetrically substituted 1,1′-binaphthalene ligand.
应用
(R)-(+)-2′-Amino-1,1′-binaphthalen-2-ol may be used as a catalyst in the asymmetric PTC (phase-transfer catalysis) synthesis of α-amino acids. (R)-NOBIN reacts with trans-azobenzene-4,4′-dicarbonyl chloride to form poly(ester-amide)s, which shows backbone light-regulated chiroptical response.
包装
Bottomless glass bottle. Contents are inside inserted fused cone.
警示用语：
Danger
危险声明
危险分类
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Stimuli-responsive polymers. 10. Photo-regulation of optical rotations in azobenzene modified poly (ester-amide) s containing highly structured, atropisomeric backbone geometries.
Lynch JG and Jaycox GD.
Polymer, 55(16), 3564-3572 (2014)
Highly Efficient Catalytic Synthesis of a-Amino Acids under Phase-Transfer Conditions with a Novel Catalyst/Substrate Pair.
Belokon YN, et al.
Angewandte Chemie (International Edition in English), 40(10), 1948-1951 (2001)
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