所有图片(1)

文件

713678

1,5-Cyclooctadiene{[dibenzyl((4S,5S)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]dicyclohexylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate

Name: 1,5-Cyclooctadiene{[dibenzyl((4<I>S</I>,5<I>S</I>)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]dicyclohexylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate
Brand: ALDRICH

97%

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所有图片(1)

别名:

Ubaphox, [((4S,5S)-Cy2-Ubaphox)Ir(COD)]BARF

经验公式（希尔记法）:

C₇₇H₇₀BF₂₄IrNO₂P

CAS号:

583844-38-6

分子量:

1731.35

MDL编号:

MFCD06658139

UNSPSC代码:

12352101

PubChem化学物质编号:

329763209

NACRES:

NA.22

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Slide 1 of 10

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Sigma-Aldrich

713570

1,5-Cyclooctadiene{[dibenzyl((4R,5R)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]dicyclohexylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate

Sigma-Aldrich

688533

(S)-2-[2-[双(2-甲苯基)膦]苯基]-4-叔丁基-2-噁唑啉

Sigma-Aldrich

691097

1,5-Cyclooctadiene{[dibenzyl((4S,5S)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]diphenylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate

Sigma-Aldrich

688495

(S)-4-叔丁基-2-[2-(二苯基膦基)苯基]-2-噁唑啉

Sigma-Aldrich

719641

(4S)-2-[2-(二苯基膦)苯基]-4,5-二氢-5,5-二甲基-4-(1-甲基乙基)-噁唑

Sigma-Aldrich

693774

双(环辛二烯)四(3,5-双(三氟甲基)苯基)硼酸铱(I)

Sigma-Aldrich

72575

(R)-(+)-2-[2-(二苯基膦)苯基]-4-异丙基-2-噁唑啉

Sigma-Aldrich

683094

HS157

Sigma-Aldrich

257443

氟乙腈

Sigma-Aldrich

682322

(R)-N-二苯基膦-N-甲基-(S)-2-(二苯基膦)二茂铁基乙胺

质量水平

100

检测方案

97%

形式

powder

光学纯度

ee: ≥99%

SMILES字符串

[Ir+].[CH]1[CH]CC[CH][CH]CC1.C[C@@H]2OC(=N[C@@H]2C(Cc3ccccc3)(Cc4ccccc4)OP(C5CCCCC5)C6CCCCC6)c7ccccc7.FC(F)(F)c8cc(cc(c8)C(F)(F)F)[B-](c9cc(cc(c9)C(F)(F)F)C(F)(F)F)(c%10cc(cc(c%10)C(F)(F)F)C(F)(F)F)c%11cc(cc(c%11)C(F)(F)F)C(F)(F)F

InChI

1S/C37H46NO2P.C32H12BF24.C8H12.Ir/c1-29-35(38-36(39-29)32-21-11-4-12-22-32)37(27-30-17-7-2-8-18-30,28-31-19-9-3-10-20-31)40-41(33-23-13-5-14-24-33)34-25-15-6-16-26-34;34-25(35,36)13-1-14(26(37,38)39)6-21(5-13)33(22-7-15(27(40,41)42)2-16(8-22)28(43,44)45,23-9-17(29(46,47)48)3-18(10-23)30(49,50)51)24-11-19(31(52,53)54)4-20(12-24)32(55,56)57;1-2-4-6-8-7-5-3-1;/h2-4,7-12,17-22,29,33-35H,5-6,13-16,23-28H2,1H3;1-12H;1-2,7-8H,3-6H2;/q;-1;;+1/b;;2-1-,8-7-;/t29-,35-;;;/m0.../s1

InChI key

BGPHLJWQZLLYML-RDSUWHNOSA-N

一般描述

sold in collaboration with Solvias AG

应用

Catalyst for enantioselective hydrogenation of alkenes

包装

Bottomless glass bottle. Contents are inside inserted fused cone.

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

分析证书(COA)

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A New Class of Modular Phosphinite-Oxazoline Ligands: Ir-Catalyzed Enantioselective Hydrogenation of Alkenes We thank Dr. Martin Studer and Dr. Benoît Pugin (Solvias AG, Basel) for fruitful discussions, and Prof. Kevin Burgess (Texas A&M University) for preprints of related unpublished work. Financial support by the Swiss National Science Foundation is gratefully acknowledged.

Jörg Blankenstein et al.

Angewandte Chemie (International ed. in English), 40(23), 4445-4447 (2002-10-31)

Threonine-derived phosphinite-oxazoline ligands for the Ir-catalyzed enantioselective hydrogenation.

Menges, F. and Pfaltz, A.

Advanced Synthesis & Catalysis, 344, 40-44 (2002)

文件

1,5-Cyclooctadiene{[dibenzyl((4S,5S)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]dicyclohexylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate

97%

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属性

质量水平

检测方案

形式

光学纯度

SMILES字符串

InChI

InChI key

相关类别

说明

一般描述

应用

包装

安全信息

WGK

闪点(°F)

闪点(°C)

个人防护装备

文件

分析证书(COA)

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