713066
1-丁基-3-甲基咪唑碘化物
99%
别名:
BMIMI
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关于此项目
经验公式（希尔记法）:
C8H15IN2
化学文摘社编号:
分子量:
266.12
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
5836286
Assay:
≥98.5% (HPLC), 99%
Form:
liquid
InChI
1S/C8H15N2.HI/c1-3-4-5-10-7-6-9(2)8-10;/h6-8H,3-5H2,1-2H3;1H/q+1;/p-1
InChI key
XREPTGNZZKNFQZ-UHFFFAOYSA-M
SMILES string
[I-].CCCCn1cc[n+](C)c1
assay
≥98.5% (HPLC), 99%
form
liquid
impurities
≤0.5% water
anion traces
bromide (Br-): ≤25 mg/kg, chloride (Cl-): ≤25 mg/kg, fluoride (F-): ≤10 mg/kg, nitrate (NO3-): ≤25 mg/kg, sulfate (SO42-): ≤10 mg/kg
Quality Level
General description
1-丁基-3-甲基咪唑碘化物是一种室温离子液体（RTIL）。
Application
BMImI可用作染料敏化光化学电池中的非挥发性电解质。它还可以用作稳定剂/促进剂/反应介质，用于过渡金属催化的β-氨基醇和2-氨基苯酚的双相氧化环羰基化反应，形成相应的2-恶唑烷酮。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
433.4 °F - closed cup
flash_point_c
223 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
In situ low temperature polymerization of bismaleimide for gel-type electrolyte for dye-sensitized solar cells
Chen, Jian-Ging, et al.
The Journal of Physical Chemistry C, 114.32, 13832-13837 (2010)
Theoretical and spectroscopic studies of 1-butyl-3-methylimidazolium iodide room temperature ionic liquid: Its differences with chloride and bromide derivatives.
Shukla M, et al.
Journal of Molecular Structure, 975(1), 349-356 (2010)
Development of 151Eu Time-Domain Interferometry and Its Application for the Study of Slow Dynamics in Ionic Liquids
Saito, Makina, et al.
Applied Physics Express, 2.2, 026502-026502 (2009)
Stella D Nickerson et al.
The journal of physical chemistry. B, 119(28), 8764-8772 (2015-06-20)
Iodide-based ionic liquids have been widely employed as iodide sources in electrolytes for applications utilizing the triiodide/iodide redox couple. While adding a low-viscosity solvent such as water to ionic liquids can greatly enhance their usefulness, mixtures of highly viscous iodide-containing
Pd(Phen)Cl2 stabilized by ionic liquid: an efficient and reusable catalyst for biphasic oxidative cyclocarbonylation of ?-aminoalcohols and 2-aminophenol.
Li F and Xia C.
Tetrahedron Letters, 48(28), 4845-4848 (2007)
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