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Merck
CN

713066

Sigma-Aldrich

1-丁基-3-甲基咪唑碘化物

99%

别名:

BMIMI

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About This Item

经验公式(希尔记法):
C8H15IN2
CAS号:
分子量:
266.12
Beilstein:
5836286
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

≥98.5% (HPLC)
99%

表单

liquid

杂质

≤0.5% water

痕量阴离子

bromide (Br-): ≤25 mg/kg
chloride (Cl-): ≤25 mg/kg
fluoride (F-): ≤10 mg/kg
nitrate (NO3-): ≤25 mg/kg
sulfate (SO42-): ≤10 mg/kg

SMILES字符串

[I-].CCCCn1cc[n+](C)c1

InChI

1S/C8H15N2.HI/c1-3-4-5-10-7-6-9(2)8-10;/h6-8H,3-5H2,1-2H3;1H/q+1;/p-1

InChI key

XREPTGNZZKNFQZ-UHFFFAOYSA-M

一般描述

1-丁基-3-甲基咪唑碘化物是一种室温离子液体(RTIL)。

应用

BMImI可用作染料敏化光化学电池中的非挥发性电解质。它还可以用作稳定剂/促进剂/反应介质,用于过渡金属催化的β-氨基醇和2-氨基苯酚的双相氧化环羰基化反应,形成相应的2-恶唑烷酮。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Oral - Eye Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

433.4 °F - closed cup

闪点(°C)

223 °C - closed cup

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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访问文档库

Theoretical and spectroscopic studies of 1-butyl-3-methylimidazolium iodide room temperature ionic liquid: Its differences with chloride and bromide derivatives.
Shukla M, et al.
Journal of Molecular Structure, 975(1), 349-356 (2010)
In situ low temperature polymerization of bismaleimide for gel-type electrolyte for dye-sensitized solar cells
Chen, Jian-Ging, et al.
The Journal of Physical Chemistry C, 114.32, 13832-13837 (2010)
Stella D Nickerson et al.
The journal of physical chemistry. B, 119(28), 8764-8772 (2015-06-20)
Iodide-based ionic liquids have been widely employed as iodide sources in electrolytes for applications utilizing the triiodide/iodide redox couple. While adding a low-viscosity solvent such as water to ionic liquids can greatly enhance their usefulness, mixtures of highly viscous iodide-containing
Pd(Phen)Cl2 stabilized by ionic liquid: an efficient and reusable catalyst for biphasic oxidative cyclocarbonylation of ?-aminoalcohols and 2-aminophenol.
Li F and Xia C.
Tetrahedron Letters, 48(28), 4845-4848 (2007)
Development of 151Eu Time-Domain Interferometry and Its Application for the Study of Slow Dynamics in Ionic Liquids
Saito, Makina, et al.
Applied Physics Express, 2.2, 026502-026502 (2009)

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