产品名称
三氯化铁 溶液, 0.2 M in 2-methyltetrahydrofuran
表单
solution
质量水平
反应适用性
core: iron
reagent type: catalyst
环保替代产品特性
Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
浓度
0.2 M in 2-methyltetrahydrofuran
折射率
n20/D 1.414
密度
0.868 g/mL at 25 °C
环保替代产品分类
, Aligned
SMILES字符串
Cl[Fe](Cl)Cl
InChI
1S/3ClH.Fe/h3*1H;/q;;;+3/p-3
InChI key
RBTARNINKXHZNM-UHFFFAOYSA-K
一般描述
我们致力于为您带来更加绿色的替代产品，这些产品遵守一项或多项绿色化学12项原则。凭借独特的性质，如无毒、低成本、丰度高、选择性高，FeCl3可用于许多生物质转化过程。该产品在2-甲基四氢呋喃中的浓度为0.2 M，因此符合“更安全的溶剂和助剂”、“可再生原料的使用”原则，并提高了催化效率。点击此处以获取更多信息。
应用
溶于绿色溶剂2-甲基四氢呋喃 (2-MeTHF) 中的氯化铁（III）可用于：
2-甲基四氢呋喃（2-MeTHF）： 一种生物质衍生的溶剂，广泛应用于有机化学
- 作为酚醛偶联反应的温和氧化剂
- 用于芳基锂和酮烯醇化物的二聚体化
- 作为一种温和的路易斯酸催化剂催化烯反应
- Nazarov环化、迈克尔加成和丙酮化反应
2-甲基四氢呋喃（2-MeTHF）： 一种生物质衍生的溶剂，广泛应用于有机化学
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Irrit. 2
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 2
闪点(°F)
14.0 °F - closed cup
闪点(°C)
-10.0 °C - closed cup
法规信息
危险化学品
此项目有
Abdelwareth A O Sarhan et al.
Chemical Society reviews, 38(9), 2730-2744 (2009-08-20)
In this critical review, the use of iron(III) chloride in oxidative C-C couplings of arenes and related unsaturated compounds is presented and reviewed. The approach allows highly selective dimerisations of phenol derivatives, naphthols, and heterocyclic compounds. Sequential couplings give access
Chen-Yu Chen et al.
Clinica chimica acta; international journal of clinical chemistry, 438, 337-341 (2014-10-05)
Insulin-like growth factor binding protein-1 (IGFBP-1) constitutes a subgroup of the insulin-like growth factor binding protein systems, and its concentration in amniotic fluid is 100-1000 times higher than the concentration in other body fluids. The aim of this study was
Xiaoqing Li et al.
The Journal of organic chemistry, 78(18), 9499-9504 (2013-08-28)
Halosulfonylation of terminal alkynes was achieved with sulfonylhydrazides as the sulfonyl precursor and inexpensive iron halide as halide source in the presence of TBHP, allowing the regio- and stereoselective generation of (E)-β-chloro and bromo vinylsulfones.
M Golder et al.
Thrombosis and haemostasis, 109(1), 53-60 (2012-11-28)
Factor VIII (FVIII), a procoagulant cofactor, plays a crucial role in the intrinsic coagulation cascade. A causal association between elevated FVIII levels and venous thrombosis incidence has been established; no such association has been confirmed with arterial thrombosis. The independent
Dattatraya H Dethe et al.
Organic letters, 15(3), 429-431 (2013-01-16)
A novel approach was developed for the synthesis of highly substituted indene derivatives, using an FeCl(3) catalyzed Prins-type cyclization reaction which was further applied in the total synthesis of jungianol and epi-jungianol.
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