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Merck
CN

710857

Sigma-Aldrich

三氯化铁 溶液

greener alternative

0.2 M in 2-methyltetrahydrofuran

别名:

氯化铁 溶液

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About This Item

线性分子式:
FeCl3
CAS号:
分子量:
162.20
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22

表单

solution

质量水平

反应适用性

core: iron
reagent type: catalyst

环保替代产品特性

Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

浓度

0.2 M in 2-methyltetrahydrofuran

折射率

n20/D 1.414

密度

0.868 g/mL at 25 °C

环保替代产品分类

SMILES字符串

Cl[Fe](Cl)Cl

InChI

1S/3ClH.Fe/h3*1H;/q;;;+3/p-3

InChI key

RBTARNINKXHZNM-UHFFFAOYSA-K

一般描述

我们致力于为您带来更加绿色的替代产品,这些产品遵守一项或多项绿色化学12项原则。凭借独特的性质,如无毒、低成本、丰度高、选择性高,FeCl3可用于许多生物质转化过程。该产品在2-甲基四氢呋喃中的浓度为0.2 M,因此符合“更安全的溶剂和助剂”、“可再生原料的使用”原则,并提高了催化效率。点击此处以获取更多信息。

应用

溶于绿色溶剂2-甲基四氢呋喃 (2-MeTHF) 中的氯化铁(III)可用于:
  • 作为酚醛偶联反应的温和氧化剂
  • 用于芳基锂和酮烯醇化物的二聚体化
  • 作为一种温和的路易斯酸催化剂催化烯反应
  • Nazarov环化、迈克尔加成和丙酮化反应


2-甲基四氢呋喃(2-MeTHF): 一种生物质衍生的溶剂,广泛应用于有机化学

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Irrit. 2

补充剂危害

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

14.0 °F - closed cup

闪点(°C)

-10.0 °C - closed cup

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Abdelwareth A O Sarhan et al.
Chemical Society reviews, 38(9), 2730-2744 (2009-08-20)
In this critical review, the use of iron(III) chloride in oxidative C-C couplings of arenes and related unsaturated compounds is presented and reviewed. The approach allows highly selective dimerisations of phenol derivatives, naphthols, and heterocyclic compounds. Sequential couplings give access
Chen-Yu Chen et al.
Clinica chimica acta; international journal of clinical chemistry, 438, 337-341 (2014-10-05)
Insulin-like growth factor binding protein-1 (IGFBP-1) constitutes a subgroup of the insulin-like growth factor binding protein systems, and its concentration in amniotic fluid is 100-1000 times higher than the concentration in other body fluids. The aim of this study was
D C Florian Wieland et al.
Colloids and surfaces. B, Biointerfaces, 109, 74-81 (2013-04-27)
The early stages of the formation of inorganic aggregates, composed of iron compounds at the solution-air interface, were investigated in situ. The properties of the solution-air interface were changed by using different Langmuir layers. In order to get insight into
Dattatraya H Dethe et al.
Organic letters, 15(3), 429-431 (2013-01-16)
A novel approach was developed for the synthesis of highly substituted indene derivatives, using an FeCl(3) catalyzed Prins-type cyclization reaction which was further applied in the total synthesis of jungianol and epi-jungianol.
Justin D Barr et al.
Blood, 121(18), 3733-3741 (2013-01-25)
Application of ferric chloride (FeCl(3)) to exposed blood vessels is widely used to initiate thrombosis in laboratory mice. Because the mechanisms by which FeCl(3) induces endothelial injury and subsequent thrombus formation are little understood, we used scanning electron and brightfield

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