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Merck
CN

70869

Sigma-Aldrich

1-丁基-2,3-二甲基咪唑六氟磷酸盐

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About This Item

经验公式(希尔记法):
C9H17F6N2P
分子量:
298.21
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:

方案

≥97.0% (HPLC)
≥97.0%

表单

liquid

密度

1.345 g/mL at 20 °C (lit.)

SMILES字符串

F[P-](F)(F)(F)(F)F.CCCCn1cc[n+](C)c1C

InChI

1S/C9H17N2.F6P/c1-4-5-6-11-8-7-10(3)9(11)2;1-7(2,3,4,5)6/h7-8H,4-6H2,1-3H3;/q+1;-1

InChI key

JWFPQAXAGSAKRF-UHFFFAOYSA-N

应用

1-Butyl-2,3-dimethylimidazolium hexafluorophosphate is an ionic liquid that can be used:
  • As a green solvent in the separation of endosulfan from water.
  • As a binder in the preparation of carbon paste electrode, applicable in the detection of adenosine-5′-triphosphate in injection samples.
  • As a component of the biphasic medium along with toluene, used in norbornene ring-opening metathesis polymerization.

外形

离子液体

其他说明

离子液体,适用于强碱性环境,如羟醛缩合和复分解反应

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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First ring-opening metathesis polymerization in an ionic liquid. Efficient recycling of a catalyst generated from a cationic ruthenium allenylidene complex
Csihony S, et al.
New. J. Chem., 26(11), 1667-1670 (2002)
Sensitive Electrochemical Determination of Adenosine-5′-triphosphate with 1-Butyl-2, 3-dimethylimidazolium Hexafluorophosphate Based Carbon Paste Electrode
Wei L, et al.
International Journal of Electrochemical Science, 14(11), 10070-10078 (2019)
1-Butyl-2, 3-dimethylimidazolium hexafluorophosphate as a green solvent for the extraction of endosulfan from aqueous solution using supported liquid membrane
Pilli SR, et al.
Chemical Engineering Journal, 257, 56-65 (2014)
S. Csihony et al.
New. J. Chem., 26, 1667-1667 (2002)
Priya A Thomas et al.
International journal of molecular sciences, 12(6), 3989-3997 (2011-07-13)
The self-metathesis of methyl oleate and methyl ricinoleate was carried out in the presence of ruthenium alkylidene catalysts 1-4 in [bmim] and [bdmim][X] type ionic liquids (RTILs) (X = PF(6) (-), BF(4) (-) and NTf(2) (-)) using the gas chromatographic

商品

Functionalized imidazolium cations with thioether, urea, or thiourea derivatized side chains act as metal-ligating moieties, whereas the PF6– anions provide the desired water immiscibility.

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