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708682

RuCl[(R,R)-TsDPEN](均三甲苯)

Name: RuCl[(<I>R</I>,<I>R</I>)-TsDPEN](均三甲苯)
Brand: ALDRICH

90%

别名:

[N-[(1R,2R)-2-(氨基-κN)-1,2-二苯乙基]-4-甲基苯磺酰胺合-κN]氯[(1,2,3,4,5,6-η)-1,3,5-三甲苯]-钌

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About This Item

经验公式（希尔记法）:

C₃₀H₃₃ClN₂O₂RuS

CAS号:

174813-82-2

分子量:

622.18

MDL编号:

MFCD12545951

UNSPSC代码:

12352116

PubChem化学物质编号:

329762817

NACRES:

NA.22

质量水平

100

检测方案

90%

形式

solid

mp

241-249 °C

储存温度

2-8°C

SMILES字符串

Cc1cc(C)cc(C)c1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@@H]([C@H](N)c3ccccc3)c4ccccc4

InChI

1S/C21H21N2O2S.C9H12.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-7-4-8(2)6-9(3)5-7;;/h2-15,20-21H,22H2,1H3;4-6H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1

InChI key

XBNBOGZUDCYNOJ-AGEKDOICSA-M

应用

Takasago Ligands and Complexes for Asymmetric Reactions

RuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize:

(2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH).
Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.

法律信息

与 Takasago 合作销售，仅用于研究目的。WO9720789

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

分析证书(COA)

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Stereoselective Synthesis of Substituted Tetrahydropyrans and Isochromans by Cyclization of Phenylseleno Alcohols.

Temperini A, et al.

The Journal of Organic Chemistry, 80(16), 8102-8112 (2015)

Dynamic Kinetic Resolution-Based Asymmetric Transfer Hydrogenation of 2-Benzoylmorpholinones and Its Use in Concise Stereoselective Synthesis of All Four Stereoisomers of the Antidepressant Reboxetine.

Son SM and Lee HK.

The Journal of Organic Chemistry, 78(17), 8396-8404 (2013)

商品

Takasago Ligands

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

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