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方案
97%
表单
solid
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
mp
205-210 °C
官能团
phosphine
SMILES字符串
CC(C)c1cccc(C(C)C)c1N2CCN(c3c(cccc3C(C)C)C(C)C)[PH]2=O
InChI
1S/C26H39N2OP/c1-17(2)21-11-9-12-22(18(3)4)25(21)27-15-16-28(30(27)29)26-23(19(5)6)13-10-14-24(26)20(7)8/h9-14,17-20,30H,15-16H2,1-8H3
InChI key
SQYNIVDXVZPMLW-UHFFFAOYSA-N
应用
Reactnat for synthesis of air-stable palladium HASPO complexes
Catalyst for:
Catalyst for:
- Dehydrative direct arylations of arenes
- Aryl-(hetero)aryl coupling by activation of C-Cl and C-F bonds
与钌共同用于芳烃与酚脱水直接芳基化的配体
储存分类代码
11 - Combustible Solids
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
Lutz Ackermann et al.
Organic letters, 10(21), 5043-5045 (2008-10-16)
Phenols can be employed as proelectrophiles in operationally simple ruthenium-catalyzed dehydrative direct arylations, proceeding through chemo- and regioselective functionalizations of C-H and C-OH bonds.
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