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Merck
CN

707503

Sigma-Aldrich

小能隙富勒烯

greener alternative
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UNSPSC代码:
12352103
NACRES:
NA.23

形式

granular

分子量

average Mw ~1,000

组成

fullerenes, ≥80%

环保替代产品特性

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

>400 °C

溶解性

organic solvents: soluble

环保替代产品分类

SMILES字符串

C=1=C2c3c4C=1c5c6c7c8c9c%10c%11c%12c%13C%14=[C]%10=C%15c%16c%17c%14c%18c%13c%19c%20c%12c%21c%11c(c%22c%23c%24c(C2=[C]7%15%22)c%25c3c%26c%27c4c%28c5c(c6%16)c%29c%17c%30c%18c%31c%19c%32c%20c(c%21%23)c%33c%24c%34c%25c%26c%35c%36c%27c%28c%29c%37c%30c%31c%38c%32c%33c%34c%35c%38c%36%37)c89

一般描述

Insoluble small gap fullerenes can be extracted into organic solvents by simple chemical redox process.
Small gap fullerenes are higher order fullerenes with low HOMO − LUMO gaps. These allotropes of carbon are also known as metallofullerenes. They are kinetically unstable and are considered as insoluble small band gap structures. They can be extracted into organic solvents by chemical redox processes.
Small gap fullerenes, also known as giant fullerenes, possess small energy differences between the valence band and the conduction band or between the filled and unfilled energy states of individual fullerene molecules.
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应用

Small gap fullerenes can be used as doping agents on polyaniline (PANI) for organic electronics applications.

法律信息

TDA Research, Inc. 产品,美国专利 6,517,799 和 6,303,016。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

法规信息

新产品

分析证书(COA)

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Chemical redox recovery of giant, small-gap and other fullerenes
Raebiger JW, et al.
Carbon, 49(1), 37-46 (2011)
Optical, structural and electrical properties of polyaniline systems doped with C60 and small gap C60 fullerenes
Politakos N, et al.
Materials Chemistry and Physics, 142(1), 387-394 (2013)
Chemical redox recovery of giant, small-gap and other fullerenes
Raebiger, J.W.; Alford, J.M.; Bolskar, R.D.; Diener, M.D.
Carbon, 49, 37-46 (2011)
Small-bandgap endohedral metallofullerenes in high yield and purity.
Stevenson S, et al.
Nature, 401(6748), 55-55 (1999)
Isolation and properties of small-bandgap fullerenes.
Diener MD and Alford JM
Nature, 393(6686), 668-668 (1998)

商品

Find various photovoltaic and bioscience-based applications of fullerenes.

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