707163
(1S,4S)-2,5-二苯基二环[2,2,2]辛-2,5-二烯
95%
别名:
(S,S)-苯基-Bod
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关于此项目
经验公式（希尔记法）:
C20H18
化学文摘社编号:
分子量:
258.36
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352002
MDL number:
产品名称
(1S,4S)-2,5-二苯基二环[2,2,2]辛-2,5-二烯, 95%
InChI
1S/C20H18/c1-3-7-15(8-4-1)19-13-18-12-11-17(19)14-20(18)16-9-5-2-6-10-16/h1-10,13-14,17-18H,11-12H2/t17-,18-/m0/s1
SMILES string
C1C[C@H]2C=C([C@@H]1C=C2c3ccccc3)c4ccccc4
InChI key
BDYBOFJAEBJDMI-ROUUACIJSA-N
assay
95%
form
solid
optical activity
[α]22/D +34.0°, c = 0.7 in chloroform
mp
69-76 °C
functional group
phenyl
storage temp.
−20°C
Quality Level
Application
(1S,4S)-2,5-二苯基二环[2,2,2]辛-2,5-二烯可作为手性二烯配体用于制备1-甲氧基-5,6,9,10-四氢[6]螺烯。
signalword
Warning
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Nickel-Catalyzed Construction of Chiral 1-[6] Helicenols and Application in the Synthesis of [6] Helicene-Based Phosphinite Ligands
Tsujihara T, et al.
European Journal of Organic Chemistry, 2016(29), 4948-4952 (2016)
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