所有图片(1)
About This Item
经验公式(希尔记法):
C17H32N2OSn
CAS号:
分子量:
399.16
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
95%
表单
liquid
折射率
n20/D 1.507
沸点
293 °C
密度
1.164 g/mL at 25 °C
SMILES字符串
CCCC[Sn](CCCC)(CCCC)c1nccc(OC)n1
InChI
1S/C5H5N2O.3C4H9.Sn/c1-8-5-2-3-6-4-7-5;3*1-3-4-2;/h2-3H,1H3;3*1,3-4H2,2H3;
InChI key
HQUSEOSQVFRYQV-UHFFFAOYSA-N
一般描述
6-Methoxy-2-(tributylstannyl)pyrimidine is an organotin compound used in Stille coupling reaction.
应用
6-Methoxy-2-(tributylstannyl)pyrimidine can be used as a reactant for the preparation of substituted pyrimidinone compounds via a Stille coupling reaction with aryl bromides. It can be also employed for the preparation of 4-methoxy-2-phenylpyrimidine by reacting with iodobenzene using Pd as a catalyst.
警示用语:
Danger
危险分类
Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Synthesis of Mono-and Diaza-`Pyridones? via Stille Coupling of Alkoxystannanes
Smith CL, et al.
Synlett, 25(13), 1904-1908 (2014)
Synthesis of new polyaza heterocycles. Part 42: Diazines
Darabantu M, et al.
Tetrahedron, 61(11), 2897-2905 (2005)
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