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Merck
CN

706515

Sigma-Aldrich

一氢化铜 (CuH) 溶液

in toluene

别名:

(BDP)Cu(H), 一氢化铜, 氢化亚铜

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About This Item

线性分子式:
CuH
CAS号:
分子量:
64.55
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.22

表单

liquid

反应适用性

core: copper
reagent type: catalyst

浓度

in toluene

储存温度

−20°C

SMILES字符串

[CuH]

InChI

1S/Cu.H

InChI key

JJFLDSOAQUJVBF-UHFFFAOYSA-N

应用

Reagent for stereoselective synthesis of exocyclic tetra substituted enol ethers and olefins

警示用语:

Danger

危险分类

Aquatic Chronic 3 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

靶器官

Central nervous system

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

42.8 °F

闪点(°C)

6 °C

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Benjamin A Baker et al.
Organic letters, 10(2), 289-292 (2007-12-21)
A ligand-modified, economical version of Stryker's reagent (SR) has been developed based on a bidentate, achiral bis-phosphine. Generated in situ, "(BDP)CuH" smoothly effects conjugate reductions of a variety of unsaturated substrates, including those that are normally unreactive toward SR. Substrate-to-ligand
Niklas O Thiel et al.
Organic & biomolecular chemistry, 14(45), 10660-10666 (2016-10-27)
An air-stable and preactivated copper(i) hydroxide/N-heteroyclic carbene (NHC) complex for alkyne semihydrogenations is reported. Next to an enhanced practicability of the process, the resulting alkenes are obtained with high Z-selectivities and no overreduction to the corresponding alkanes.

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