推荐产品
表单
liquid
反应适用性
core: copper
reagent type: catalyst
浓度
in toluene
储存温度
−20°C
SMILES字符串
[CuH]
InChI
1S/Cu.H
InChI key
JJFLDSOAQUJVBF-UHFFFAOYSA-N
应用
Reagent for stereoselective synthesis of exocyclic tetra substituted enol ethers and olefins
警示用语:
Danger
危险分类
Aquatic Chronic 3 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
靶器官
Central nervous system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
42.8 °F
闪点(°C)
6 °C
法规信息
新产品
Benjamin A Baker et al.
Organic letters, 10(2), 289-292 (2007-12-21)
A ligand-modified, economical version of Stryker's reagent (SR) has been developed based on a bidentate, achiral bis-phosphine. Generated in situ, "(BDP)CuH" smoothly effects conjugate reductions of a variety of unsaturated substrates, including those that are normally unreactive toward SR. Substrate-to-ligand
Niklas O Thiel et al.
Organic & biomolecular chemistry, 14(45), 10660-10666 (2016-10-27)
An air-stable and preactivated copper(i) hydroxide/N-heteroyclic carbene (NHC) complex for alkyne semihydrogenations is reported. Next to an enhanced practicability of the process, the resulting alkenes are obtained with high Z-selectivities and no overreduction to the corresponding alkanes.
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