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Merck
CN
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安全信息

704946

Sigma-Aldrich

氯(2-二环己基膦基-2′,6′-二甲氧基-1,1′-联苯基)[2-(2-氨基乙基苯基)]钯(II) - 甲基--叔丁基醚加合物

别名:

(2-二环己基膦基-2′,6′-二甲氧基-1,1′-联苯基)[2-(2-氨基乙基苯基)]氯化钯(II) - 甲基-叔-丁基醚加合物, (SPhos) 钯(II) 苯乙胺氯化物（1:1 MTBE 溶剂化物）

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About This Item

线性分子式:
C34H45ClNO2PPd · CH3OC4H9
分子量:
760.72
MDL编号:
MFCD15144765
UNSPSC代码:
12161600
PubChem化学物质编号:
329762493
NACRES:
NA.22

表单

solid

质量水平

100

特点

generation 1

反应适用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings

mp

160-170 °C

官能团

phosphine

SMILES字符串

COC(C)(C)C.NCCc1ccccc1[Pd]Cl.COc2cccc(OC)c2-c3ccccc3P(C4CCCCC4)C5CCCCC5

InChI

1S/C26H35O2P.C8H10N.C5H12O.ClH.Pd/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;9-7-6-8-4-2-1-3-5-8;1-5(2,3)6-4;;/h9-11,16-21H,3-8,12-15H2,1-2H3;1-4H,6-7,9H2;1-4H3;1H;/q;;;;+1/p-1

InChI key

CLLOZWOLUBODPC-UHFFFAOYSA-M

相关类别

应用

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Catalyst for C-N bond forming reaction.

法律信息

用法以美国专利 6307087 和 6395916 为准。

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315,H319,H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

新产品

从最新的版本中选择一种：

分析证书(COA)

Lot/Batch Number
SHBQ2535
SHBH1145V
SHBC5511V
SHBB5739V
SHBB5739

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David S Surry et al.
Angewandte Chemie (International ed. in English), 47(34), 6338-6361 (2008-07-30)
Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have proven to provide especially active catalysts in this context. This Review discusses
Ruben Martin et al.
Accounts of chemical research, 41(11), 1461-1473 (2008-07-16)
The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucial to the work of a broad spectrum of organic chemists. Recently, Pd-catalyzed carbon-carbon
David S Surry et al.
Chemical science, 2(1), 27-50 (2011-01-01)
Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of the best choice of reaction conditions and ligand

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