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Merck
CN

704091

Sigma-Aldrich

三丁基氢化锡 溶液

1 M in cyclohexane

别名:

Tributylstannane, Tributylstannyl hydride

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About This Item

经验公式(希尔记法):
C12H28Sn
CAS号:
分子量:
291.06
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22

表单

liquid

反应适用性

reagent type: reductant

浓度

1 M in cyclohexane

折射率

n20/D 1.438

密度

0.895 g/mL at 25 °C

SMILES字符串

CCCC[SnH](CCCC)CCCC

InChI

1S/3C4H9.Sn.H/c3*1-3-4-2;;/h3*1,3-4H2,2H3;;

InChI key

DBGVGMSCBYYSLD-UHFFFAOYSA-N

应用

Reactant or reagent for:
  • Alkyne hydrostannations
  • Intramolcular cyclization for the synthesis of zoanthamine alkaloids
  • Stereoselective C-glycosylation of pyranosides using Heck allylation
  • Synthesis of phenylbutenoid dimers for use in treating diseases
  • Preparation of N-acyl derivatives of ecteinascidin 770
  • Syntehsis of cyclonucleosides using black light induced radical cyclization

闪点(°F)

5.0 °F

闪点(°C)

-15 °C

法规信息

监管及禁止进口产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Cassander P Titley-O'Neal et al.
The Science of the total environment, 449, 52-62 (2013-02-16)
Queen conch (Strombus gigas) are listed in CITES Appendix II. Populations may be declining due to anthropogenic inputs that include pollutants from boating activity. In the British Virgin Islands (BVI), some conch exhibit imposex, a condition in which male external
Shanshan Zhu et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 921-922, 21-26 (2013-02-19)
Analysis of tributyltin chloride (TBT) in environmental samples, such as seawater, is important in order to evaluate the TBT contamination and accumulation in the trophic chain. The environmental impact of organotin compounds has been a particular focus of analytical studies.
Robert W Chapman et al.
Molecular ecology, 22(6), 1485-1487 (2013-04-20)
Reproduction is the goal of living organisms, and environmental conditions that influence sexual development are therefore critical to understanding adaptation in natural populations. It is not surprising that so much attention has been devoted to the impacts of the physical
Detection, monitoring, and control of tributyltin--an almost complete success story.
Peter Matthiessen
Environmental toxicology and chemistry, 32(3), 487-489 (2013-02-19)
Ang Yu et al.
Aquatic toxicology (Amsterdam, Netherlands), 128-129, 158-162 (2013-01-15)
Tributyltin (TBT) is a ubiquitous marine contaminant due to its extensive use as a biocide, fungicide and antifouling agent. However, the neurotoxic effect of TBT has not been extensively studied, especially in marine fish. This study was conducted to investigate

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