701211
乙酰丙酮酰双(亚乙基)化铑(I)
95%, solid
别名:
Bis(η2-ethene)(2,4-pentanedionato-κO,κO′)-rhodium, Bis(ethylene)rhodium(I) acetylacetonate, 乙酰丙酮二(乙烯)铑, 乙酰丙酮二乙烯铑配合物, 二(乙烯)乙酰丙酮铑
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关于此项目
经验公式（希尔记法）:
C9H15O2Rh
化学文摘社编号:
分子量:
258.12
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
235-147-1
MDL number:
产品名称
乙酰丙酮酰双(亚乙基)化铑(I), 95%
InChI key
FLRBEQQDEGBCJS-FGSKAQBVSA-M
InChI
1S/C5H8O2.2C2H4.Rh/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;2*1-2H2;/q;;;+1/p-1/b4-3-;;;
SMILES string
C=C.C=C.CC(=O)\C=C(\C)O[Rh]
assay
95%
form
solid
reaction suitability
core: rhodium
reagent type: catalyst
mp
141-142 °C
storage temp.
2-8°C
Quality Level
General description
Acetylacetonatobis(ethylene)rhodium(I) is a coordination compound commonly used as a precursor to synthesize mononuclear rhodium complexes. In addition, it is also used as a catalyst in asymmetric arylation reactions.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Rhodium complex with ethylene ligands supported on highly dehydroxylated MgO: synthesis, characterization, and reactivity
Bhirud VA, et al.
Langmuir, 22(1), 490-496 (2006)
Rhodium-catalyzed asymmetric phenylation of N-phosphinoylarylimines with triphenylborane
Hao X, et al.
Catalysis Science & Technology, 1(1), 62-64 (2011)
Chiral bicyclic bridgehead phosphoramidite (briphos) ligands for asymmetric rhodium-catalyzed 1, 2-and 1, 4-addition
Lee A, et al.
The Journal of Organic Chemistry, 81(9) , 3520-3527 (2016)
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