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Merck
CN

700479

Sigma-Aldrich

甲基丙烯酸二茂铁基甲酯

95% (NMR), contains Ionol® 46 (Raschig GmbH) as inhibitor

别名:

FMMA

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About This Item

经验公式(希尔记法):
C15H16FeO2
CAS号:
分子量:
284.13
MDL编号:
UNSPSC代码:
12162002
PubChem化学物质编号:
NACRES:
NA.23

质量水平

方案

95% (NMR)

表单

solid

包含

Ionol® 46 (Raschig GmbH) as inhibitor

mp

52-54 °C

储存温度

−20°C

SMILES字符串

[Fe].[CH]1[CH][CH][CH][CH]1.CC(=C)C(=O)OC[C]2[CH][CH][CH][CH]2

InChI

1S/C10H11O2.C5H5.Fe/c1-8(2)10(11)12-7-9-5-3-4-6-9;1-2-4-5-3-1;/h3-6H,1,7H2,2H3;1-5H;

InChI key

GSPYKNCYLXXOJO-UHFFFAOYSA-N

法律信息

Ionol is a registered trademark of Raschig GmbH

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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  1. How does the storage temperature relate to shipping conditions?

    The storage conditions that a Sigma-Aldrich catalog and label recommend for products are deliberately conservative. For many products, long-term storage at low temperatures will increase the time during which they are expected to remain in specification and therefore are labeled accordingly. Where short-term storage, shipping time frame, or exposure to conditions other than those recommended for long-term storage will not affect product quality, Sigma-Aldrich will ship at ambient temperature. The products sensitive to short-term exposure to conditions other than their recommended long-term storage are shipped on wet or dry ice. Ambient temperature shipping helps to control shipping costs for our customers. At any time, our customers can request wet- or dry-ice shipment, but the special handling is at customer expense if our product history indicates that the product is stable for regular shipment. See Shipping and Storage for more information.

  2. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  3. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  4. How do I find price and availability?

    There are several ways to find pricing and availability for our products. Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers.

  5. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  6. What is the inhibitor used in Product No. 700479, Ferrocenylmethyl methacrylate?

    The inhibitor used in this product is 2,2´-methylenebis(6-tert-butyl-4-methylphenol) (CAS registry number [119-47-1]), which is a non-discoloring and non-staining stabilizer. It is widely used in industry especially in natural and synthetic rubber.

  7. How can the monomer ferrocenylmethyl methacrylate, Product 700479, be polymerized?

    Generally, Product No. 700479 can be polymerized with an anionic initiator such as butyllithium (Product No. 230707) or lithium aluminum hydride (Product No. 531502). Or it can be radically polymerized using an initiator such as 2,2´-Azobis(2-methylpropionitrile) (AIBN, Product No. 44109).

  8. What applications can Product 700479,  Ferrocenylmethyl methacrylate, be used for?

    Thin films of poly- ferrocenylmethyl methacrylate can be used for biosensing applications, taking advantage of the redox behavior of the ferrocenyl unit.

  9. My question is not addressed here, how can I contact Technical Service for assistance?

    Ask a Scientist here.

Yoonhee Na et al.
Journal of materials chemistry. B, 8(9), 1906-1913 (2020-02-12)
Ferrocene-containing nanoparticles show reversible redox activity that could trigger drug release mediated by reactive oxygen species (ROS). In this study, four ferrocene-containing polymers, comprising ferrocenylmethyl methacrylate (FMMA)-methacrylic acid (MA) random copolymers, i.e., poly(FMMA-r-MA), were synthesized via radical polymerization, resulting in
Antonio Preti et al.
Social psychiatry and psychiatric epidemiology, 54(3), 355-367 (2018-12-14)
Paranoid thoughts are relatively common in the general population and can increase the risk of developing mental health conditions. In this study, we investigate the latent structure of paranoia in a sample of young people. Cross-sectional survey; 243 undergraduate students
Yoonhee Na et al.
International journal of pharmaceutics, 596, 120205-120205 (2021-01-25)
The elevated production of reactive oxygen species (ROS) in wounded sites triggers a series of harmful effects, including cellular senescence, fibrotic scar formation, and inflammation. Therefore, alleviating oxidative stress in the microenvironment of wounded sites might promote regenerative wound healing.
Hoik Lee et al.
Polymers, 12(11) (2020-11-04)
We demonstrate an electrospray/electrospinning process to fabricate stimuli-responsive nanofibers or particles that can be utilized as stimuli-responsive drug-loaded materials. A series of random copolymers consisting of hydrophobic ferrocene monomers and hydrophilic carboxyl groups, namely poly(ferrocenylmethyl methacrylate-r-methacrylic acid) [poly(FMMA-r-MA)] with varied
Liying Zhao et al.
Biosensors & bioelectronics, 150, 111895-111895 (2019-11-25)
Cytokeratin fragment antigen 21-1 (CYFRA 21-1) DNA is a crucial biomarker closely associated with non-small cell lung cancer. Here, we fabricated a novel electrochemical biosensor for ultrasensitive detection of CYFRA 21-1 DNA via polysaccharide and electrochemically mediated atom transfer radical

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