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About This Item
经验公式（希尔记法）:
C31H48F3O3P2RhS
CAS号:
分子量:
722.62
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
形式
powder
SMILES字符串
[Rh+].[O-]S(=O)(=O)C(F)(F)F.C1CC=CCCC=C1.CC[C@H]2CC[C@H](CC)P2c3ccccc3P4[C@@H](CC)CC[C@@H]4CC
InChI
1S/C22H36P2.C8H12.CHF3O3S.Rh/c1-5-17-13-14-18(6-2)23(17)21-11-9-10-12-22(21)24-19(7-3)15-16-20(24)8-4;1-2-4-6-8-7-5-3-1;2-1(3,4)8(5,6)7;/h9-12,17-20H,5-8,13-16H2,1-4H3;1-2,7-8H,3-6H2;(H,5,6,7);/q;;;+1/p-1/b;2-1-,8-7-;;/t17-,18-,19-,20-;;;/m0.../s1
InChI key
HZLILTNLWVOBFS-ZCTOJWETSA-M
一般描述
1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate is an electron-rich C2 symmetric bis(phospholane) ligand for enantioselective catalytic reactions.
应用
DuPhos and BPE Ligands: Highly Efficient Privileged Ligands
Catalyst involved in:
Catalyst involved in:
- Oxidation of the δ-position via ruthenium catalysis
- Stereoselective hydrogenation reactions of dehydroamino acid esters and macrocyclic peptideomimetics
- Synthesis of cyclopeptide alkaloid mucronine E, fluoro-containing amino acids, and labeled protease inhibitors
(S,S)-Et-DUPHOS-Rh may be used as an efficient catalyst in the synthesis of (S)-2-quinolylalanine via asymmetric hydrogenation.
法律信息
与 Kanata Chemical Technologies Inc. 联合销售，仅供研究使用。这些化合物由 E.I. du Pont de Nemours and Company 授权制造和销售，此许可不包括利用这些化合物制备在制药领域销售的产品的权利。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
DuPhos and BPE Phospholane Ligands and Complexes
Aldrich Chemfiles, 8(2), 34-34 (2008)
Preparation of (S)-2-quinolylalanine by asymmetric hydrogenation.
Jones SW, et al.
Tetrahedron Letters, 40(6), 1211-1214 (1999)
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