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形式
liquid
质量水平
反应适用性
core: copper
reagent type: catalyst
浓度
in anhydrous tetrahydrofuran
密度
0.999 g/mL at 25 °C
SMILES字符串
[Li]Cl.[Li]Cl.[Cu]C#N
InChI
1S/CN.2ClH.Cu.2Li/c1-2;;;;;/h;2*1H;;;/q;;;;2*+1/p-2
InChI key
QGXKBLXNBYNHBV-UHFFFAOYSA-L
应用
氰化亚铜（I）二（氯化锂）配合物可用于，通过有机锌 和格氏（Grignard）试剂的转移金属化合成有机铜（I）试剂。 也是制备有机铜（I）试剂的有用前体。
警示用语：
Danger
危险分类
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Central nervous system, Respiratory system
补充剂危害
WGK
WGK 2
闪点(°F)
Solvent
闪点(°C)
Solvent
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
TMPZnCl?LiCl: A new active selective base for the directed zincation of sensitive aromatics and heteroaromatics.
Mosrin M and Knochel P
Organic Letters, 11(8), 1837-1840 (2009)
Joel M Harris et al.
The Journal of organic chemistry, 68(11), 4371-4381 (2003-05-24)
2,5,6-Trisubstituted piperidines are readily prepared by a combination of an aza-Achmatowicz oxidation of a furyl-substituted benzenesulfonamide followed by a conjugate addition to the resulting 2H-pyridone and subsequent addition of various nucleophiles to a transient N-sulfonyliminium ion. The stereochemistry of the
Regioselective functionalization of trisubstituted pyridines using a bromine-magnesium exchange.
Ren H and Knochel P
Chemical Communications (Cambridge, England), 11(7), 726-728 (2006)
Krause, N.; Gerold, A.
Angewandte Chemie (International Edition in English), 36, 186-186 (1997)
Tomas Hudlicky et al.
The Journal of organic chemistry, 67(25), 8726-8743 (2002-12-07)
Biocatalytic approaches have yielded efficient total syntheses of the major Amaryllidaceae alkaloids, all based on the key enzymatic dioxygenation of suitable aromatic precursors. This paper discusses the logic of general synthetic design for lycoricidine, narciclasine, pancratistatin, and 7-deoxypancratistatin. Experimental details
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